反应条件
in tetrahydrofuran
under N2, soln. of freshly prepd. CpFeC5H4Li in THF added at -78°C to soln. of Mn(CO)Br in THF, warmed to room temp., stirred for 1.5 h; evapd. in vac., extd. with toluene, evapd., sepd. by column chromy. (Kieselgel (Matrex TM 60, 70-200 μ); pentane, CH2Cl2, CH2Cl2/Et2O (1/1)), recrystd. at -78°C from pentane (Mn(CO)5(CpFeC5H4)) or CH2Cl2/pentane (others); elem. anal.;
参考文献
Herberhold, Max; Kniesel, Heidemarie
Journal of Organometallic Chemistry, 1987 , vol. 334, p. 347 - 358
