1.1: [Rh(1,5-COD)(S,S-Et-FerroTANE)]BF4; hydrogen / ethyl acetate / 16 h / 60 °C / 3750.38 Torr 2.1: hydrogenchloride; water / 30 - 90 °C 2.2: 40 - 47 °C / pH 4 View Scheme

1.1: [Rh(1,5-COD)(S,S-Et-FerroTANE)]BF4; hydrogen / ethyl acetate / 16 h / 60 °C / 3750.38 Torr 2.1: 4-(N,N-dimethlyamino)pyridine / tetrahydrofuran / 16 h / 20 °C 2.2: 5 h / 20 °C 2.3: pH 4 View Scheme

Multi-step reaction with 3 steps 1.1: hydrogenchloride; KIO3; potassium iodide / methanol; water / 0 - 20 °C / Large scale reaction2.1: pyridine / 10 °C2.2: 39 - 55 °C / Large scale reaction3.1: palladium diacetate; triethylamine; tris-(o-tolyl)phosphine