1,4-二(十二烷氧基)-2,5-二碘苯合成路线 （共 12 条）
反应条件
KIO3; sulfuric acid; iodine in acetic acid T=120°C;
参考文献
Gonzalez-Rojano, Norma; Arias-Marin, Eduardo; Navarro-Rodriguez, Damaso; Weidner, Steffen
Synlett, 2005 , # 8 art. no. S01505ST, p. 1259 - 1262
反应条件
1: 67 percent / K2CO3 / dimethylformamide 2: 60 percent / iodine; iodic acid; H2SO4 / acetic acid / CCl4; H2O / 3 h / 75 °C View Scheme
参考文献
Gonzalez-Rojano, Norma; Arias-Marin, Eduardo; Navarro-Rodriguez, Damaso; Weidner, Steffen
Synlett, 2005 , # 8 art. no. S01505ST, p. 1259 - 1262
反应条件
1: 67 percent / K2CO3 / dimethylformamide 2: 60 percent / iodine; iodic acid; H2SO4 / acetic acid / CCl4; H2O / 3 h / 75 °C View Scheme
参考文献
Gonzalez-Rojano, Norma; Arias-Marin, Eduardo; Navarro-Rodriguez, Damaso; Weidner, Steffen
Synlett, 2005 , # 8 art. no. S01505ST, p. 1259 - 1262
反应条件
potassium carbonate in N,N-dimethyl-formamide T=100°C; 18 h; Inert atmosphere;
参考文献
Masai, Hiroshi; Terao, Jun; Seki, Shu; Nakashima, Shigeto; Kiguchi, Manabu; Okoshi, Kento; Fujihara, Tetsuaki; Tsuji, Yasushi
Journal of the American Chemical Society, 2014 , vol. 136, # 5 p. 1742 - 1745
反应条件
potassium hydroxide in ethanol 24 h; Reflux;
参考文献
Xu, Shaoan; Das, Sanjib; Ogi, Soichiro; Sugiyasu, Kazunori; Okazaki, Hiroyuki; Takano, Yoshihiko; Yasuda, Takeshi; Deguchi, Kenzo; Ohki, Shinobu; Shimizu, Tadashi; Takeuchi, Masayuki
Chemistry - A European Journal, 2013 , vol. 19, # 19 p. 5824 - 5829
反应条件
trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) in toluene T=90°C; Stille reaction; 39 h;
参考文献
Daoud, Walid A.; Turner, Michael L.
Bulletin of the Chemical Society of Japan, 2005 , vol. 78, # 2 p. 367 - 369
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran T=60°C; Sonogashira coupling; 12 h; Inert atmosphere;
参考文献
Yin, Shouchun; Leen, Volker; Jackers, Carine; Beljonne, David; Van Averbeke, Bernard; Van Der Auweraer, Mark; Boens, Noel; Dehaen, Wim
Chemistry - A European Journal, 2011 , vol. 17, # 47 p. 13247 - 13257
反应条件
1: 1,4-diiodo-2,5-di(n-dodecyloxy)benzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: N,N-dimethyl-formamide in tetrahydrofuran; hexane T=-78°C; 2 h;
参考文献
Liao, Jian; Wang, Qing
Macromolecules, 2004 , vol. 37, # 18 p. 7061 - 7063
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran
T=40°C; Sonogashira coupling; 24 h;
参考文献
Morisaki, Yasuhiro; Chujo, Yoshiki
Macromolecules, 2003 , vol. 36, # 25 p. 9319 - 9324
反应条件
copper(l) iodide; diisopropylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
T=20°C; 24 h;
参考文献
Zhao, Jinling; Bo, Zhishan
Synthetic Communications, 2005 , vol. 35, # 10 p. 1391 - 1402
