2-苯基-2,4,6-环庚三烯-1-酮合成路线 （共 22 条）
参考文献
Nozoe et al.
Sci. Rep. Tohoku Univ., Ser. 1: Phys., Chem., Astron., 1953 , vol. # 37, p. 419,388,397
反应条件
1: aq. CuSO4 / benzene 2: aq. H2SO4 View Scheme
参考文献
Kikuchi,K.
Bulletin of the Chemical Society of Japan, 1967 , vol. 40, p. 385 - 388
反应条件
palladium diacetate; sodium acetate T=80°C; 10 h;
参考文献
Saito, Katsuhiro
Journal of Organometallic Chemistry, 1988 , vol. 338, p. 265 - 268
反应条件
bis-triphenylphosphine-palladium(II) chloride; caesium carbonate in tetrahydrofuran; water
T=75°C; Suzuki Coupling; 16 h; Inert atmosphere;
参考文献
UNIVERSITY OF CONNECTICUT; WRIGHT, Dennis L.; ANDERSON, Amy C.; VAN HEYST, Michael; ONONYE, Sophia
Patent: WO2013/192554 A1, 2013 ;
Location in patent: Page/Page column 15 ;
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; 2,6-di-tert-butyl-4-methyl-phenol; lithium chloride in N,N-dimethyl-formamide
T=70°C; 23 h; Molecular sieveInert atmosphere;
参考文献
Rivero, Alexandra R.; Fernandez, Israel; Sierra, Miguel Angel
Organic Letters, 2013 , vol. 15, # 19 p. 4928 - 4931
反应条件
tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0); 2-dicyclohexylphosphino-1,1'-biphenyl in tetrahydrofuran
6 h; Heating;
参考文献
Seganish, W. Michael; DeShong, Philip
Journal of Organic Chemistry, 2004 , vol. 69, # 4 p. 1137 - 1143
反应条件
1: 64 percent / pyridine / 12 h / 20 °C
2: 89 percent / Pd(dba)2; 2-dicyclohexylphosphinobiphenyl; TBAF / tetrahydrofuran / 6 h / Heating
View Scheme
参考文献
Seganish, W. Michael; DeShong, Philip
Journal of Organic Chemistry, 2004 , vol. 69, # 4 p. 1137 - 1143
反应条件
palladium diacetate; sodium acetate
T=80°C; 6 h;
参考文献
Saito, Katsuhiro
Journal of Organometallic Chemistry, 1988 , vol. 338, p. 265 - 268
反应条件
1: 27 percent / Pd(OAc)2, NaOAc / benzene / 8 h / 80 °C
2: 14 percent / Pd(OAc)2, NaOAc / 6 h / 80 °C
View Scheme
参考文献
Saito, Katsuhiro
Journal of Organometallic Chemistry, 1988 , vol. 338, p. 265 - 268
反应条件
1: diethyl ether; tetrahydrofuran
2: aq. H2SO4 / 140 - 150 °C
3: Ac2O
View Scheme
参考文献
Kikuchi,K.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1610 - 1615
