1-[(3R)-3-羟基-1-环己烯-1-基]乙酮合成路线 （共 4 条）
反应条件
toluene-4-sulfonic acid in water; acetone T=40°C; 2.5 h;
参考文献
Hagiwara, Hisahiro; Nakano, Takashi; Kon-no, Masakazu; Uda, Hisashi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 7 p. 777 - 784
反应条件
1: 1.) LDA / 1.) THF, -60 deg C, 10 min, 2.) THF, -60 deg C, 5 min 2: 2-methyl-propan-2-ol / 0.17 h / Ambient temperature 3: m-CPBA / CH2Cl2 / 0.17 h / 0 °C 4: 10percent aq. KOH / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Satoh, Tsuyoshi; Motohashi, Shigeyasu; Tokutake, Norio; Yamakawa, Koji
Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 2966 - 2973
反应条件
1: m-CPBA / CH2Cl2 / 0.17 h / 0 °C 2: 10percent aq. KOH / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Satoh, Tsuyoshi; Motohashi, Shigeyasu; Tokutake, Norio; Yamakawa, Koji
Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 2966 - 2973
反应条件
1: 2-methyl-propan-2-ol / 0.17 h / Ambient temperature 2: m-CPBA / CH2Cl2 / 0.17 h / 0 °C 3: 10percent aq. KOH / methanol / 0.25 h / Ambient temperature View Scheme
参考文献
Satoh, Tsuyoshi; Motohashi, Shigeyasu; Tokutake, Norio; Yamakawa, Koji
Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 11 p. 2966 - 2973
