2-环戊烯-1-基(三甲基)硅烷合成路线 （共 7 条）
反应条件
magnesium in tetrahydrofuran 1.) 0 deg C, irradiation, 30 min, 2.) 40-50 deg C, 4 h;
参考文献
Hagen, Gisela; Mayr, Herbert
Journal of the American Chemical Society, 1991 , vol. 113, # 13 p. 4954 - 4961
反应条件
1: in tetrahydrofuran 18 h; RefluxInert atmosphere; 2: With water in tetrahydrofuran T=0°C;
参考文献
Yoshimura, Yuichi; Ohta, Masatoshi; Imahori, Tatsushi; Imamichi, Tomozumi; Takahata, Hiroki
Organic Letters, 2008 , vol. 10, # 16 p. 3449 - 3452
反应条件
trimethylsilyl trifluoromethanesulfonate; [bis(acetoxy)iodo]benzene in dichloromethane T=20°C; 1 h;
参考文献
Yoshimura, Yuichi; Ohta, Masatoshi; Imahori, Tatsushi; Imamichi, Tomozumi; Takahata, Hiroki
Organic Letters, 2008 , vol. 10, # 16 p. 3449 - 3452
反应条件
1: 63 percent / BF3*Et2O / CH2Cl2 / 1) -78 deg C, 15 min, 2) r.t., 3-6 h 2: 76 percent / H2 / 10percent Pd/C / ethanol; tetrahydrofuran / 17 h / 2068.6 Torr View Scheme
参考文献
Roos, Eric C.; Mooiweer, Hendrik H.; Hiemstra, Henk; Speckamp, W. Nico; Kaptein, Bernard; et al.
Journal of Organic Chemistry, 1992 , vol. 57, # 25 p. 6769 - 6778
反应条件
1: 63 percent / BF3*Et2O / CH2Cl2 / 1) -78 deg C, 15 min, 2) r.t., 3-6 h 2: 76 percent / H2 / 10percent Pd/C / ethanol; tetrahydrofuran / 17 h / 2068.6 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 57, # 25 p. 6769 - 6778
反应条件
1: 74 percent Spectr. / singlet O2 / methanol / 0.5 h / 40 °C / Irradiation
2: 60 percent / MnO2/active C / 408 h
View Scheme
参考文献
Dubac, J.; Laporterie, A.; Iloughmane, H.; Pillot, J. P.; Deleris, G.; Dunogues, J.
Journal of Organometallic Chemistry, 1985 , vol. 281, p. 149 - 162
反应条件
trimethylsilyl trifluoromethanesulfonate in dichloromethane
1.) -78 deg C, 15 min, 2.) r.t., 4 h;
参考文献
Roos; Lopez; Brook; Hiemstra; Speckamp
Journal of Organic Chemistry, 1993 , vol. 58, # 12 p. 3259 - 3268
