1,2,4-三(1,1-二甲基乙基)苯合成路线 (共 6 条)
反应条件
η5-cyclopentadienyl dicarbonyl cobalt in water T=380°C; P=187515 Torr; 2 h; cyclotrimerization of acetylenes; Product distributionMechanism;
参考文献
Borwieck; Walter; Dinjus; Rebizant
Journal of Organometallic Chemistry, 1998 , vol. 570, # 1 p. 121 - 127
反应条件
ethylene glycol dimethyl ether; NbCl3 in 1,2-dichloro-ethane T=40°C; 4 h; Inert atmosphere; regioselective reaction;
参考文献
Obora, Yasushi; Takeshita, Keisuke; Ishii, Yasutaka
Organic and Biomolecular Chemistry, 2009 , vol. 7, # 3 p. 428 - 431
反应条件
ethylene glycol dimethyl ether; NbCl3 in 1,2-dichloro-ethane T=40°C; 3 h; chemoselective reaction;
参考文献
Satoh, Yasushi; Obora, Yasushi
Journal of Organic Chemistry, 2011 , vol. 76, # 20 p. 8569 - 8573
反应条件
tris-(trimethylsilyl)silane; niobium pentachloride in 1,2-dichloro-ethane T=40°C; 3 h; Inert atmosphere; regioselective reaction;
参考文献
Satoh, Yasushi; Obora, Yasushi
Journal of Organic Chemistry, 2011 , vol. 76, # 20 p. 8569 - 8573
反应条件
4-bromooctafluorobutanetriethoxysilane; niobium pentachloride in 1,2-dichloro-ethane T=40°C; 3 h; chemoselective reaction;
参考文献
Satoh, Yasushi; Obora, Yasushi
Journal of Organic Chemistry, 2011 , vol. 76, # 20 p. 8569 - 8573
反应条件
copper(l) iodide; oxygen Yield given. Multistep reaction;
参考文献
Kuenzer,Hermann; Berger, Stefan
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3222 - 3223