1,3,5-三叔丁基苯合成路线 （共 102 条）
反应条件
1: 85 percent / Ph3P, diethylazidoformate, LiBr / tetrahydrofuran / 24 h / Ambient temperature 2: 1.) Mg, 2.) PCl3 / 1.) Et2O, RT, 3 h, ultrasonic irrad., 2.) Et2O, from -78 deg C to RT 3: LiAlH4 / diethyl ether / 0.5 h / Heating View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 67, # 7 p. 1980 - 1983
反应条件
1: 1.) Mg, 2.) PCl3 / 1.) Et2O, RT, 3 h, ultrasonic irrad., 2.) Et2O, from -78 deg C to RT 2: LiAlH4 / diethyl ether / 0.5 h / Heating View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 67, # 7 p. 1980 - 1983
反应条件
1: 64 percent / BH3*THF / tetrahydrofuran / 15 h / Ambient temperature 2: 85 percent / Ph3P, diethylazidoformate, LiBr / tetrahydrofuran / 24 h / Ambient temperature 3: 1.) Mg, 2.) PCl3 / 1.) Et2O, RT, 3 h, ultrasonic irrad., 2.) Et2O, from -78 deg C to RT 4: LiAlH4 / diethyl ether / 0.5 h / Heating View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 67, # 7 p. 1980 - 1983
反应条件
tris-(trimethylsilyl)silane; niobium pentachloride in 1,2-dichloro-ethane T=40°C; 3 h; Inert atmosphere; regioselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 76, # 20 p. 8569 - 8573
反应条件
4-bromooctafluorobutanetriethoxysilane; niobium pentachloride in 1,2-dichloro-ethane T=40°C; 3 h; chemoselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 76, # 20 p. 8569 - 8573
反应条件
tetrafluoroboric acid; n-heptane T=-30°C;
反应条件
lithium aluminium tetrahydride in diethyl ether 0.5 h; Yield given. Yields of byproduct given;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 67, # 7 p. 1980 - 1983
反应条件
(MDMCp)Co(COD) T=100°C; 6 h;
参考文献
Journal of Organometallic Chemistry, , vol. 619, # 1-2 p. 179 - 193
反应条件
1: 80 percent / NaN3 / dimethylformamide; pyridine / Heating 2: aq. HCl / CHCl3 / 2 h / 20 °C View Scheme
参考文献
Journal of the Chemical Society, Chemical Communications, , # 22 p. 1197 - 1198
反应条件
aluminium trichloride; water in carbon disulfide Rearrangement;
参考文献
Organic Preparations and Procedures International, , vol. 23, # 4 p. 425 - 427
