5,6,11,12-四氢二苯并[a,e]环辛烯合成路线 （共 46 条）
反应条件
diethyl benzenedicarboxylate
T=300°C;
参考文献
Cava; Deana
Journal of the American Chemical Society, 1959 , vol. 81, p. 4266
参考文献
Wong,H.N.C. et al.
Journal of the American Chemical Society, 1974 , vol. 96, # 17 p. 5604 - 5605
反应条件
potassium fluoride in N,N-dimethyl-formamide
T=80°C;
参考文献
Kuwano, Ryoichi; Shige, Takenori
Chemistry Letters, 2005 , vol. 34, # 5 p. 728 - 729
反应条件
sodium in 1,4-dioxane
52 h; Heating; Further byproducts given;
参考文献
Domiano, Paolo; Cozzini, Pietro; Claramunt, Rosa Maria; Lavandera, Jose Luis; Sanz, Dionisia; Elguero, Jose
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1992 , # 9 p. 1609 - 1620
反应条件
palladium on activated charcoal; acetic acid
Hydrogenation;
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
参考文献
Ito, Yoshihiko; Nakajo, Eiji; Sho, Katsuhiko; Saegusa, Takeo
Synthesis, 1985 , # 6/7 p. 698 - 699
反应条件
1: NaBH4; methanol; aqueous NaOH
2: H3BO3 / 205 °C / 0.5 Torr
3: palladium/charcoal; cyclohexane / Hydrogenation
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: H3BO3 / 205 °C / 0.5 Torr
2: palladium/charcoal; cyclohexane / Hydrogenation
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: polyphosphoric acid
2: NaBH4; methanol; aqueous NaOH
3: H3BO3 / 205 °C / 0.5 Torr
4: palladium/charcoal; cyclohexane / Hydrogenation
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
反应条件
1: 2-methyl-pyridine
2: palladium/charcoal; cyclohexane / Hydrogenation
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
