hydroxide in water; dimethyl sulfoxide
T=25°C; further reagent; Rate constantMechanism;
参考文献
Cho, Bong Rae; Lee, Jong Chan; Cho, Nam Soon; Kim, Kee Dong
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 489 - 492
in water; acetonitrile
T=25°C; nucleophilic substitution reactions of p-nitrophenyl acetate with normal nucleophile and α-nucleophiles; various MeCN-H2O compositions; relative reactivity of the nucleophiles; solvent effect on reactivity, basicity; effect of solvent on α-effect; Rate constant;
hydroxide in water; dimethyl sulfoxide
T=25°C; further reagent; Rate constantMechanism;
参考文献
Cho, Bong Rae; Lee, Jong Chan; Cho, Nam Soon; Kim, Kee Dong
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 489 - 492