in dichloromethane (N2); addn. of Sn-compd. to mixt. of 1 equiv. EtCHO and 1 equiv. BCl3 in CH2Cl2 at -78°C, warming to room temperature, standing (4 h); treatment with sat. aq. NH4Cl;
参考文献
Journal of Organometallic Chemistry, , vol. 390, # 2 p. 127 - 138
in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in an exothermic reaction with N2 evolution; allowing to stand for 24 h at 20°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 232, # 2 p. 137 - 146
CH3COCl byproducts: CH3COOC(CH3)CHCH(CH3)2; very exothermic react.;
参考文献
Pereyre, M.; Valade, J.
Bulletin de la Societe Chimique de France, 1967 , p. 1928 - 1936
Full Text Show Details
Gmelin Handbook: Sn: Org.Comp.12, 1.4.1.1.1.5.2.2, page 97 - 113
