in not given byproducts: ethyl acetate; excess of acetyl chloride added to Bu3SnCH(OEt)2 under N2, stirred at room temp. for 1.5 h, volatiles removed in vacuo; identified by NMR spectra;
参考文献
Journal of Organometallic Chemistry, , vol. 251, # 2 p. 175 - 188
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3, (t-C4H9)(i-C3H7)PSi2Cl5; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 2.5 h; (119)Sn- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 75 d; (119)Sn- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
in pentane (under N2, Schlenk); soln. of SnCl4 in pentane added to soln. of Sn-complex in pentane, stirred for 16 h at room temp.; filtered, washed with pentane, dried in vacuo, volatiles removed in vacuo; monitored by NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 691, # 8 p. 1544 - 1553
