tetrakis(triphenylphosphine) palladium(0) in not given byproducts: acetophenone;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 58, # 3 p. 1075 - 1076
→
反应条件
bromine in tetrachloromethane (ratio Sn-compd./Br2 1/1, in the dark, 30 min, room temp.); not isolated; NMR monitoring; ratio of erythro/threo isomers 70/30;
参考文献
Journal of Organometallic Chemistry, , vol. 376, p. 283 - 296
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-Me-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-Cl-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (24 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: m-Me-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-MeO-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: o-MeCO-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (20 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: o-MeO-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-CN-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (20 h); evapn., chromy. (silica gel), reduced pressure distn.;
trans-[(2-tolyl)3P]2PdCl2 in xylene byproducts: p-NO2-C6H4-CH2CN; mixt. of degassed educts heated at 120°C, until the color of mixt. turning to black (3 h); evapn., chromy. (silica gel), reduced pressure distn.;
