in tetrahydrofuran; n-heptane byproducts: CH3S(O)2CH2Mg(s-Bu); under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in heptane, SnMe4 (internal standard) and THF mixed; reacted for1 h; not isolated; monitored by (119)Sn NMR spectra; > 95percent conversion;
参考文献
Journal of Organometallic Chemistry, , vol. 655, # 1-2 p. 111 - 114
in tetrahydrofuran; n-heptane byproducts: C6H5S(O)CH2Mg(s-Bu); under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in heptane, SnMe4 (internal standard) and THF mixed; reacted for1 h; not isolated; monitored by (119)Sn NMR spectra; > 95percent conversion;
参考文献
Journal of Organometallic Chemistry, , vol. 655, # 1-2 p. 111 - 114
in tetrahydrofuran; diethyl ether byproducts: CH3S(O)2CH2MgBr; under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in Et2O, SnMe4 (internal standard) and THF mixed; reacted for 1 h; not isolated; monitored by (119)Sn NMR spectra; 80-95percent conversion;
参考文献
Journal of Organometallic Chemistry, , vol. 655, # 1-2 p. 111 - 114
in tetrahydrofuran; diethyl ether byproducts: C6H5S(O)CH2MgBr; under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in Et2O, SnMe4 (internal standard) and THF mixed; reacted for 1 h; not isolated; monitored by (119)Sn NMR spectra; > 95percent conversion;
参考文献
Journal of Organometallic Chemistry, , vol. 655, # 1-2 p. 111 - 114
in tetrahydrofuran; diethyl ether byproducts: Ph2P(O)2CH2MgBr; under anaerobic conditions, in NMR tube; Sn compd., Mg compd. (molar ratio 1:1) in Et2O, SnMe4 (internal standard) and THF mixed; not isolated; monitored by (119)Sn NMR spectra; quantitative conversion;
参考文献
Journal of Organometallic Chemistry, , vol. 655, # 1-2 p. 111 - 114
Nobis, J. F.; Moormeier, L. F.; Robinson, R. E.
Advances in Chemistry Series, 1959 , vol. 23, p. 63 - 68
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Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.5.1, page 94 - 98
