戊烷基-2-乙酰氨基-3,4,6-三-O-乙酰基-2-脱氧-β-D-葡萄糖苷合成路线 （共 9 条）
反应条件
1: β-D-GlcNAc tetraacetate With trimethylsilyl trifluoromethanesulfonate; sodium hydrogencarbonate in chloroform; water T=20°C; 5 h; 2: pentan-1-ol With camphor-10-sulfonic acid in 1,2-dichloro-ethane T=60°C; 2 h;
参考文献
Kanebo Cosmetics Inc.
Patent: EP1553101 A1, 2005 ;
Location in patent: Page/Page column 14-15 ;
反应条件
1: 76.8 percent / SnCl4 / CH2Cl2 / 15 h 2: BuNH2 / ethanol / Heating 3: 250 mg / pyridine / 25 °C View Scheme
参考文献
Ats, Sandor-Csaba; Lehmann, Jochen; Petry, Stefan
Carbohydrate Research, 1992 , vol. 233, p. 125 - 139
反应条件
1: 76.8 percent / SnCl4 / CH2Cl2 / 15 h 2: BuNH2 / ethanol / Heating 3: 250 mg / pyridine / 25 °C View Scheme
参考文献
Ats, Sandor-Csaba; Lehmann, Jochen; Petry, Stefan
Carbohydrate Research, 1992 , vol. 233, p. 125 - 139
反应条件
15-crown-5; sodium iodide in 1,2-dichloro-ethane T=70°C; Title compound not separated from byproducts;
参考文献
Kur'yanov; Zemlyakov; Chupakhina; Chirva
Russian Journal of Bioorganic Chemistry, 1998 , vol. 24, # 4 p. 282 - 283
反应条件
1: BuNH2 / ethanol / Heating 2: 250 mg / pyridine / 25 °C View Scheme
参考文献
Ats, Sandor-Csaba; Lehmann, Jochen; Petry, Stefan
Carbohydrate Research, 1992 , vol. 233, p. 125 - 139
参考文献
Ats, Sandor-Csaba; Lehmann, Jochen; Petry, Stefan
Carbohydrate Research, 1992 , vol. 233, p. 125 - 139
反应条件
15-crown-5; sodium iodide in 1,2-dichloro-ethane Ambient temperature;
参考文献
Kur'yanov; Zemlyakov; Chupakhina; Chirva
Russian Journal of Bioorganic Chemistry, 1998 , vol. 24, # 4 p. 282 - 283
反应条件
15-crown-5; sodium iodide Ambient temperatureother alcohols, var. temp.;
参考文献
Kur'yanov; Zemlyakov; Chupakhina; Chirva
Russian Journal of Bioorganic Chemistry, 1998 , vol. 24, # 4 p. 282 - 283
反应条件
sodium methylate in methanol
T=25°C;
参考文献
Ats, Sandor-Csaba; Lehmann, Jochen; Petry, Stefan
Carbohydrate Research, 1992 , vol. 233, p. 125 - 139
