二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
(Me2SiCp''2UBu)2O*2THF in tetrahydrofuran T=66°C; 65 h; Product distribution; Further Variations:reaction time;
参考文献
Journal of the American Chemical Society, , vol. 128, # 29 p. 9350 - 9351
反应条件
(Me2SiCp''2UBu)2O*2THF in tetrahydrofuran T=66°C; 26 h; Product distribution; Further Variations:reaction time;
参考文献
Journal of the American Chemical Society, , vol. 128, # 29 p. 9350 - 9351
反应条件
iron(III) chloride in octane T=25°C; Product distribution;
参考文献
Braun, Jacques; Trung, Bui Khac
Bulletin de la Societe Chimique de France, 1983 , vol. 2, # 1-2 p. 16 - 20
反应条件
18-crown-6 ether; cesium fluoride in benzene T=20°C; 6 h;
参考文献
Journal of Organometallic Chemistry, , vol. 634, # 1 p. 69 - 73
反应条件
(Me2SiCp''2UBu)2O*2THF in tetrahydrofuran T=66°C; 4 h; Product distribution; Further Variations:reaction time;
参考文献
Journal of the American Chemical Society, , vol. 128, # 29 p. 9350 - 9351
反应条件
1: 75 percent / AlCl3 / CH2Cl2 / 12 h / Ambient temperature 2: 85 percent / tetrahydrofuran / 1.) -78 deg C, 2 h; 2.) up to RT View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 285, p. 121 - 136
反应条件
1: 94 percent / AlCl3 / CH2Cl2 / 20 °C 2: 93 percent / EtMgBr / tetrahydrofuran; diethyl ether / 20 °C 3: 83 percent / n-BuLi / tetrahydrofuran; hexane; dimethylsulfoxide / -20 - 20 °C View Scheme
参考文献
Suzuki, Riho; Tsukuda, Hiroko; Watanabe, Naoto; Kuwatani, Yoshiyuki; Ueda, Ikuo
Tetrahedron, 1998 , vol. 54, # 11 p. 2477 - 2496
反应条件
aluminium trichloride in dichloromethane T=0 - 20°C; Acylation; 4 h;
参考文献
Heiss, Christian; Phillips, Robert S.
Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 16 p. 2821 - 2825
反应条件
1: With aluminium trichloride in dichloromethane T=0 - 20°C; 4 h; 2: With tetrabutyl-ammonium chloride; NAF in diethyl ether; water
参考文献
Heiss, Christian; Laivenieks, Maris; Zeikus; Phillips, Robert S.
Bioorganic and Medicinal Chemistry, 2001 , vol. 9, # 7 p. 1659 - 1666
反应条件
aluminium trichloride in dichloromethane T=20°C;
参考文献
Maurette, Luc; Tedeschi, Christine; Sermot, Emmanuelle; Soleilhavoup, Michle; Hussain, Fatima; Donnadieu, Bruno; Chauvin, Remi
Tetrahedron, 2004 , vol. 60, # 44 p. 10077 - 10098
