二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane T=20°C; Friedel-Crafts reaction; 1 h;
参考文献
Cossy; Lutz; Alauze; Meyer
Synlett, 2002 , # 1 p. 45 - 48
反应条件
1: With aluminium trichloride in dichloromethane T=0 - 20°C; 4 h; 2: With tetrabutyl-ammonium chloride; NAF in diethyl ether; water
参考文献
Heiss, Christian; Laivenieks, Maris; Zeikus; Phillips, Robert S.
Bioorganic and Medicinal Chemistry, 2001 , vol. 9, # 7 p. 1659 - 1666
反应条件
diethylaluminium chloride; titanium tetrachloride in benzene T=60°C; 6 h; in a sealed ampoule; Yield given;
参考文献
Mach, K.; Antropiusova, H.; Petrusova, L.; Turecek, F.; Hanus, V.; et al.
Journal of Organometallic Chemistry, 1985 , vol. 289, p. 331 - 340
反应条件
triethylamine T=300°C; 48 h;
参考文献
Song, Zhi Zhong; Zhou, Zhong Yuan; Mak, Thomas C. W.; Wong, Henry N. C.
Angewandte Chemie, 1993 , vol. 105, # 3 p. 406 - 408
参考文献
Ho, Mei Sing; Wong, Henry N. C.
Journal of the Chemical Society, Chemical Communications, 1989 , # 17 p. 1238 - 1240
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; triethylamine in N,N-dimethyl-formamide T=70°C; 8 h; Inert atmosphere;
参考文献
Jia, Xiaodong; Petrone, David A.; Lautens, Mark
Angewandte Chemie - International Edition, 2012 , vol. 51, # 39 p. 9870 - 9872
反应条件
iodine cloride in tetrachloromethane Ambient temperature;
参考文献
Al-Hassan, Mohammed I.
Journal of Organometallic Chemistry, 1989 , vol. 372, p. 183 - 186
反应条件
n-butyllithium 1) diethyl ether, hexane, 48 h, reflux, 2) diethyl ether, hexane, -20 deg C; 12 h., r.t.; Yield given. Multistep reaction;
参考文献
Birkofer, Leonhard; Wahle, Bernd
Chemische Berichte, 1983 , vol. 116, # 10 p. 3309 - 3315
反应条件
tetrakis(triphenylphosphine) palladium(0); copper(l) chloride in N,N-dimethyl-formamide T=80°C; sila-Sonogashira-Hagihara cross-coupling; 18 h; Inert atmosphere;
参考文献
Nishihara, Yasushi; Inoue, Eiji; Noyori, Shintaro; Ogawa, Daisuke; Okada, Yoshiaki; Iwasaki, Masayuki; Takagi, Kentaro
Tetrahedron, 2012 , vol. 68, # 24 p. 4869 - 4881
反应条件
copper(l) iodide; bis(benzonitrile)palladium(II) dichloride; (benzyl)-tri-(butyl)-ammonium chloride; sodium hydroxide; [(t-Bu)3PH]BF4 in water; toluene T=40°C; Sonogashira coupling; 22 h; Inert atmosphere;
参考文献
Bellina, Fabio; Lessi, Marco
Synlett, 2012 , vol. 23, # 5 p. 773 - 777
