二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
tetrabutylammomium bromide; palladium dichloride in water T=100°C; 8 h; Title compound not separated from byproducts;
参考文献
Gil-Molto, Juan; Najera, Carmen
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 14 p. 1874 - 1882
反应条件
HW(CO)3(C5H5) in dichloromethane-d2 T=22°C; 0.5 h; Product distribution;
参考文献
Luan, Li; Song, Jeong-Sup; Bullock, R. Morris
Journal of Organic Chemistry, 1995 , vol. 60, # 22 p. 7170 - 7176
反应条件
1: With aluminium trichloride in dichloromethane T=0 - 20°C; 4 h; 2: With tetrabutyl-ammonium chloride; NAF in diethyl ether; water
参考文献
Heiss, Christian; Laivenieks, Maris; Zeikus; Phillips, Robert S.
Bioorganic and Medicinal Chemistry, 2001 , vol. 9, # 7 p. 1659 - 1666
反应条件
in hexane a soln. of the silylalkyne added to a soln. of RuCo2(CO)11 at -78°C, warmed to room temp., stirred for 2 h; evapd. in vac., chromd. (silica gel/hexane, hexane-benzene (10:1));
参考文献
Chemische Berichte, , vol. 123, p. 661 - 666
反应条件
copper(II) sulfate
T=140 - 145°C; 10 h;
参考文献
Dolgii, I. E.; Okonnishnikova, G. P.; Ignatenko, A. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, # 4 p. 864 - 867
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , # 4 p. 947 - 950
反应条件
dihydrogen hexachloroplatinate in isopropyl alcohol
T=120 - 130°C; 47 h;
参考文献
Sheludyakov, V. D.; Korshunov, A. I.; Lakhtin, V. G.; Timofeev, V. S.; Slyusarenko, T. F.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1986 , vol. 56, # 12 p. 2743 - 2750,2429 - 2435
反应条件
platinum(0)-methyldivinyldisiloxane
T=90°C; P=760 Torr; 21 h;
参考文献
Suzuki, Toshio; Lo, Peter Y.
Journal of Organometallic Chemistry, 1990 , vol. 396, # 2/3 p. 299 - 305
反应条件
platinum(0)-tetramethyldivinyldisiloxane
T=90°C; P=760 Torr; 24 h; other disilylethynes, var. times, temp. and pressures; Product distributionMechanism;
参考文献
Suzuki, Toshio; Lo, Peter Y.
Journal of Organometallic Chemistry, 1990 , vol. 396, # 2/3 p. 299 - 305
反应条件
(i) HSiCl3, (ii) /BRN= 3587200/; Multistep reaction;
参考文献
Quass,L.C. et al.
Journal of Organometallic Chemistry, 1970 , vol. 21, p. 65 - 73
反应条件
bis(1,3-divinyl-1,1,3,3,-tetramethyldisiloxane)Pt(0)
T=130°C; 6 h; var. disilylethynes, and hydrosilanes, other times; Product distributionMechanism;
参考文献
Suzuki, Toshio; Lo, Peter Y.
Journal of Organometallic Chemistry, 1990 , vol. 391, # 1 p. 19 - 25
