二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); tetrabutyl ammonium fluoride; triethylamine in N,N-dimethyl-formamide
T=70°C; 8 h; Inert atmosphere;
参考文献
Schmidt, Bernd; Berger, Rene; Kelling, Alexandra; Schilde, Uwe
Chemistry - A European Journal, 2011 , vol. 17, # 25 p. 7032 - 7040
反应条件
1: With methyllithium in diethyl ether
T=0 - 20°C;
2: With bromine in diethyl ether; dichloromethane
T=-70°C; 0.75 h;
参考文献
Fox, Mark A.; Cameron, Audrey M.; Low, Paul J.; Paterson, Michael A.J.; Batsanov, Andrei S.; Goeta, Andres E.; Rankin, David W.H.; Robertson, Heather E.; Schirlin, Julien T.
Dalton Transactions, 2006 , # 29 p. 3544 - 3560
参考文献
Birkofer,L.; Kuehn,T.
Chemische Berichte, 1978 , vol. 111, p. 3119 - 3123
反应条件
1: With methyllithium in tetrahydrofuran
T=0 - 20°C;
2: With bromine in tetrahydrofuran; pyridine; dichloromethane
T=-78 - 20°C;
参考文献
Fox, Mark A.; Cameron, Audrey M.; Low, Paul J.; Paterson, Michael A.J.; Batsanov, Andrei S.; Goeta, Andres E.; Rankin, David W.H.; Robertson, Heather E.; Schirlin, Julien T.
Dalton Transactions, 2006 , # 29 p. 3544 - 3560
反应条件
rhodium(II) octanoate
参考文献
Kohn, Daniel W.; Chen, Peter
Journal of the American Chemical Society, 1993 , vol. 115, # 7 p. 2844 - 2848
反应条件
aluminium trichloride in carbon disulfide
T=0°C; 0.5 h;
参考文献
Bourelle-Wargnier, Francoise; Vincent, Marcel; Chuche, Josselin
Journal of Organic Chemistry, 1980 , vol. 45, # 3 p. 428 - 435
反应条件
nitronium tetrafluoroborate in nitromethane; dichloromethane
T=0 - 20°C; 1.5 h;
参考文献
Windler, G. Kenneth; Zhang, Mao-Xi; Zitterbart, Robert; Pagoria, Philip F.; Vollhardt, K. Peter C.
Chemistry - A European Journal, 2012 , vol. 18, # 21 p. 6588 - 6603
反应条件
nitronium tetrafluoroborate; tetra-n-butylammonium tetrafluoroborate; cesium fluoride in dichloromethane
2 h; Ambient temperature; Yields of byproduct given;
参考文献
Schmitt, Robert J.; Bedford, Clifford D.
Synthesis, 1986 , # 1 p. 132 - 133
反应条件
chlorine
T=22 - 68°C; 3 h;
参考文献
Lakhtin; Sheludyakov; Chernyshev
Russian Journal of General Chemistry, 2003 , vol. 73, # 5 p. 708 - 710
反应条件
chlorine; zinc(II) chloride in diethyl ether
参考文献
Birkofer,L.; Kuehn,T.
Chemische Berichte, 1978 , vol. 111, p. 3119 - 3123
