二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
1: 34.4 percent / rhodium(II) octanoate dimer
2: 91.1 percent / chlorotrimethylsilane, NaI / acetonitrile / 20 h / Heating
3: 94.1 percent / oxalyl bromide / CH2Cl2 / 25 °C
View Scheme
参考文献
Kohn, Daniel W.; Chen, Peter
Journal of the American Chemical Society, 1993 , vol. 115, # 7 p. 2844 - 2848
反应条件
1: 34.4 percent / rhodium(II) octanoate dimer
2: 91.1 percent / chlorotrimethylsilane, NaI / acetonitrile / 20 h / Heating
3: 94.1 percent / oxalyl bromide / CH2Cl2 / 25 °C
4: diethyl ether / 21 h / -78 - -30 °C
View Scheme
参考文献
Kohn, Daniel W.; Chen, Peter
Journal of the American Chemical Society, 1993 , vol. 115, # 7 p. 2844 - 2848
反应条件
1: With aluminium trichloride in dichloromethane
T=0 - 20°C; 4 h;
2: With tetrabutyl-ammonium chloride; NAF in diethyl ether; water
参考文献
Heiss, Christian; Laivenieks, Maris; Zeikus; Phillips, Robert S.
Bioorganic and Medicinal Chemistry, 2001 , vol. 9, # 7 p. 1659 - 1666
反应条件
hexacarbonyl chromium in anhydrous butyl ether
48 h; Heating;
参考文献
Chaffee, Karen; Huo, Pei; Sheridan, John B.; Barbieri, Anthony; Aistars, Arnis; Lalancette, Roger A.; Ostrander, Robert L.; Rheingold, Arnold L.
Journal of the American Chemical Society, 1995 , vol. 117, # 7 p. 1900 - 1907
反应条件
diethylaluminium chloride; titanium tetrachloride in benzene
T=60°C; 8 h; Yields of byproduct given;
参考文献
Mach, Karel; Antropiusova, Helena; Petrusova, Lidmila; Hanus, Vladimir; Turecek, Frantisek; Sedmera, Petr
Tetrahedron, 1984 , vol. 40, # 17 p. 3295 - 3302
反应条件
ammonium cerium(IV) nitrate
1) n-pentane, 5h, RT, irradiation, 2) toluene-d8, H3O; Multistep reaction;
参考文献
Fischler, Ingrid; Grevels, Friedrich-Wilhelm; Leitich, Johannes; Oezkar, Saim
Chemische Berichte, 1991 , vol. 124, # 12 p. 2857 - 2862
反应条件
diethylaluminium chloride; titanium tetrachloride
参考文献
Mach, Karel; Antropiusova, Helena; Sedmera, Petr; Hanus, Vladimir; Turecek, Frantisek
Journal of the Chemical Society, Chemical Communications, 1983 , # 15 p. 805 - 806
反应条件
η5-cyclopentadienyl dicarbonyl cobalt
5.5 h; HeatingIrradiationother alkynes; other isocyanatoalkyne;
参考文献
Earl; Vollhardt
Journal of the American Chemical Society, 1983 , vol. 105, # 23 p. 6991 - 6993
反应条件
indium tribromide in dichloromethane
T=0 - 20°C;
参考文献
Rodriguez, Ana R.; Spur, Bernd W.
Tetrahedron Letters, 2012 , vol. 53, # 1 p. 86 - 89
反应条件
AlCl3, aluminium chloride in dichloromethane
T=0°C; 0.5 h;
参考文献
Pankova, Alena S.; Golubev, Pavel R.; Kuznetsov, Mikhail A.; Ananyev, Ivan V.
European Journal of Organic Chemistry, 2012 , # 30 p. 5965 - 5971,7
