二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
in hexane under Ar, Ti complex (0.706 mmol) dissolved in hexane (10 ml), N,N-bis(trimethylsilyl)sulfurdiimide added, mixt. stirred at 50°C for 5 d; amount of solvent reduced at 0°C, distilled at 70°C and 0.1 mbar to reveal 1,2,3,4-tetramethylfulvene, n-hexane, bis(trimethylsilyl)acetylene, and N,N'-bis(trimethylsilyl)sulfurdiimide, solid dissolved in n-hexane, stored at -78°C;
参考文献
European Journal of Inorganic Chemistry, , # 21 p. 3388 - 3393
反应条件
in neat (no solvent) 135-140°C; fractionation;
参考文献
Hosmane, Narayan S.; Mollenhauer, Mark N.; Cowley, Alan H.; Norman, Nicholas C.
Organometallics, 1985 , vol. 4, p. 1194 - 1197
反应条件
in benzene 15 h; Ambient temperatureIrradiation; Title compound not separated from byproducts;
参考文献
Journal of Organometallic Chemistry, , vol. 194, # 2 p. 147 - 158
反应条件
in hexane 60 h; Ambient temperature;
参考文献
Ho, Mei Sing; Wong, Henry N. C.
Journal of the Chemical Society, Chemical Communications, 1989 , # 17 p. 1238 - 1240
反应条件
in hexane 1 h; Irradiation;
参考文献
Journal of Organometallic Chemistry, , vol. 194, # 2 p. 147 - 158
反应条件
ethylmagnesium bromide 1.) THF; Multistep reaction;
参考文献
Russian Journal of Physical Chemistry, , vol. 67, # 1 p. 47 - 51
Zhurnal Fizicheskoi Khimii, , vol. 67, # 1 p. 53 - 57
反应条件
1: toluene / 9 h / 20 °C 2: benzene-d6 / 2 h / 120 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 133, # 30 p. 11504 - 11507
反应条件
in hexane Irradiationother quenchers MeOD, t-BuOH, HOAc, acetone, O2, 1,3-octadiene; Product distributionMechanismRate constant;
参考文献
Journal of the American Chemical Society, , vol. 119, # 3 p. 466 - 471
反应条件
in hexane Irradiation; Product distributionMechanism;
参考文献
Journal of the American Chemical Society, , vol. 119, # 3 p. 466 - 471
反应条件
in benzene-d6 72 h; Inert atmosphereSchlenk technique;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 43 p. 11415 - 11419
Angew. Chem., , vol. 125, # 43 p. 11626 - 11630
