二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
sodium in diethyl ether also in the presence of other chlorosilanes; var. solvents; Product distributionMechanism;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 62, # 1.1 p. 84 - 90,68 - 73
反应条件
(i) nBuLi, (ii) /BRN= 1209232/; Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 37, p. 45 - 56
参考文献
Chemische Berichte, , vol. 92, p. 1018,1026
反应条件
in chloroform-d1; water T=4°C; 5 h; Irradiationalso without irrad.; Product distribution;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , # 4 p. 847 - 852
反应条件
tris(1,3-divinyl-1,1,3,3-tetramethyldisiloxane)-bis-platinum(0) T=130°C; 7 h; other trisilylethenes; reaction with addition of HexMe2SiH; Product distribution;
参考文献
Journal of Organometallic Chemistry, , vol. 402, # 1 p. 27 - 33
反应条件
in hexane 2 h; Ambient temperatureIrradiation;
参考文献
Journal of Organometallic Chemistry, , vol. 194, # 2 p. 147 - 158
反应条件
T=200°C; 60 h; Product distribution;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 70, # 1 p. 253 - 260
反应条件
in toluene CpCo(C2H4)2 (9.4 mmol) and Me3SiCCSiMe3 (20 mmol) dissolved in toluene and heated to reflux, at this temp. t-BuCP (7 mmol) and Me3SiCCSiMe3 (10 mmol) in toluene added over 5 h, further stirred for 2 h; filtered through Florisil, evapd., chromd. (column, Kieselgel 60, hexane), CpCo((CSiMe3)4) isolated from 1st yellow eluate, next red eluate yielded CpCo(t-BuCP(CSiMe3)2) after evapn., last eluate contained CpCo((t-BuCP)2); elem. anal.;
参考文献
Binger, Paul; Milczarek, Roman; Mynott, Richard; Regitz, Manfred
Journal of Organometallic Chemistry, 1987 , vol. 323, p. C35 - C38
反应条件
methyllithium 1.) THF, 0-25 deg C; diglyme, 25 deg C; 2.) THF, diglyme, 80 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Negishi,E.; Boardman,L.D.; Sawada,H.
Journal of the American Chemical Society, 1988 , vol. 110, p. 5383
反应条件
aluminium trichloride in carbon disulfide
参考文献
Bulletin de la Societe Chimique de France, , vol. 2, # 1-2 p. 7 - 13
