二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
bis-(trifluoromethylsulphonyl)amine in dichloromethane T=20°C; Friedel-Crafts reaction; 1 h;
参考文献
Synlett, , # 1 p. 45 - 48
反应条件
aluminium trichloride 1) CH2Cl2, 20 min, 2) CH2Cl2, 3 h, r.t.; Yield given. Multistep reaction;
参考文献
Baklouti, Mohamed; Chaabouni, Refaat; Fontanille, Michel; Villenave, Jean-Jacques
Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1451 - 1454
反应条件
aluminium trichloride 1) CH2Cl2, 20 min, 2) CH2Cl2, 5 h, r.t.; Yield given. Multistep reaction;
参考文献
Baklouti, Mohamed; Chaabouni, Refaat; Fontanille, Michel; Villenave, Jean-Jacques
Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1451 - 1454
反应条件
(Me2SiCp''2UBu)2O*2THF in tetrahydrofuran T=66°C; 23 h; Product distribution; Further Variations:reaction time;
参考文献
Wang, Jiaxi; Gurevich, Ylia; Botoshansky, Mark; Eisen, Moris S.
Journal of the American Chemical Society, 2006 , vol. 128, # 29 p. 9350 - 9351
反应条件
triethylamine byproducts: H2; TEA was added in 9 portions at -196°C, after each addition stirring 2 h at 0°C, 2 h at room temperature; then 4 days at room temperature; fractionated through traps, sepn. with fractionating volatiles;
参考文献
Hosmane, Narayan S.; Sirmokadam, Narayan N.; Mollenhauser, Mark N.
Journal of Organometallic Chemistry, 1985 , vol. 279, p. 359 - 372
反应条件
tetrabutylammomium bromide; palladium dichloride in water T=100°C; 8 h; Title compound not separated from byproducts;
参考文献
Gil-Molto, Juan; Najera, Carmen
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 14 p. 1874 - 1882
反应条件
pyrrolidine; tetrabutylammomium bromide; [5-Cl-2-{(4-Cl-phenyl)-[(E)-HO-imino]methyl}phenyl-PdCl]2 in 1-methyl-pyrrolidin-2-one T=110°C; Sila-Sonogashira coupling; 8 h;
参考文献
Alonso, Diego A.; Najera, Carmen; Pacheco, Ma. Carmen
Advanced Synthesis and Catalysis, 2003 , vol. 345, # 9-10 p. 1146 - 1158
反应条件
water in 1,4-dioxane 12 h; Heating;
参考文献
Tumer, Seniz U.; Herndon, James W.; McMullen, Leonard A.
Journal of the American Chemical Society, 1992 , vol. 114, # 22 p. 8394 - 8404
反应条件
potassium fluoride in tetrahydrofuran; water 1) reflux;
参考文献
Herndon, James W.; Tumer, Seniz U.
Tetrahedron Letters, 1989 , vol. 30, # 3 p. 295 - 296
反应条件
aluminium trichloride in dichloromethane T=20°C; 0.5 h;
参考文献
Livingston, Robert; Cox, Liam R.; Odermatt, Severin; Diederich, Franois
Helvetica Chimica Acta, 2002 , vol. 85, # 10 p. 3052 - 3077
