二(三甲基甲硅烷基)乙炔合成路线 （共 218 条）
反应条件
1: 75 percent / AlCl3 / CH2Cl2 / 12 h / Ambient temperature 2: tetrahydrofuran / 1.) -78 deg C; 2.) up to RT View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
methyllithium in tetrahydrofuran; diethyl ether T=-20 - 20°C; 2 h; Title compound not separated from byproducts;
参考文献
Brasseur, Denis; Marek, Ilane; Normant, Jean-F.
Tetrahedron, 1996 , vol. 52, # 21 p. 7235 - 7250
反应条件
diethylaluminium chloride; titanium tetrachloride in benzene T=60°C; 6 h; in a sealed ampoule; Yield given;
参考文献
Mach, K.; Antropiusova, H.; Petrusova, L.; Turecek, F.; Hanus, V.; et al.
Journal of Organometallic Chemistry, 1985 , vol. 289, p. 331 - 340
反应条件
copper(I) bromide T=134°C;
参考文献
Synthesis, , # 9 p. 871 - 873
反应条件
diethylaluminium chloride; titanium tetrachloride in benzene T=60°C; 6 h; in a sealed ampoule; Yield given;
参考文献
Mach, K.; Antropiusova, H.; Petrusova, L.; Turecek, F.; Hanus, V.; et al.
Journal of Organometallic Chemistry, 1985 , vol. 289, p. 331 - 340
反应条件
Yield given. Multistep reaction;
参考文献
Lundkvist; Vargas; Caldirola; Ringdahl; Hacksell
Journal of Medicinal Chemistry, 1990 , vol. 33, # 12 p. 3182 - 3189
反应条件
T=140°C; 0.75 h; microwave irradiation;
参考文献
Zrinski, Irena; Juribasic, Marina; Eckert-Maksic, Mirjana
Heterocycles, 2006 , vol. 68, # 9 p. 1961 - 1967
反应条件
cis-[(PPh3)2Pt(B(1,2-O2-4-tBuC6H3))2] in toluene N2-atmosphere; 80°C;
参考文献
Lesley, Gerry; Nguyen, Paul; Taylor, Nicholas J.; Marder, Todd B.; Scott, Andrew J.; Clegg, William; Norman, Nicholas C.
Organometallics, 1996 , vol. 15, # 24 p. 5137 - 5154
反应条件
pyrrolidine; tetrabutylammomium bromide; [5-Cl-2-{(4-Cl-phenyl)-[(E)-HO-imino]methyl}phenyl-PdCl]2 in 1-methyl-pyrrolidin-2-one T=130°C; Sila-Sonogashira coupling; 22 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 345, # 9-10 p. 1146 - 1158
反应条件
pyrrolidine; tetrabutylammomium bromide; [5-Cl-2-{(4-Cl-phenyl)-[(E)-HO-imino]methyl}phenyl-PdCl]2 in 1-methyl-pyrrolidin-2-one T=110°C; Sila-Sonogashira coupling; 21 h; Product distribution; Further Variations:ReagentsSolventsTemperaturesReaction partners;
参考文献
Advanced Synthesis and Catalysis, , vol. 345, # 9-10 p. 1146 - 1158
