1-三甲基甲硅烷基-3,3-二甲基-1-丁炔合成路线 （共 28 条）
反应条件
in gas
T=400°C; P=0.03 Torr; 6 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Maier, Guenther; Born, Dieter; Bauer, Ines; Wolf, Reinhard; Boese, Roland; Cremer, Dieter
Chemische Berichte, 1994 , vol. 127, # 1 p. 173 - 190
反应条件
(Me2SiCp''2UBu)2O*2THF in tetrahydrofuran
T=66°C; 65 h; Product distribution; Further Variations:reaction time;
参考文献
Wang, Jiaxi; Gurevich, Ylia; Botoshansky, Mark; Eisen, Moris S.
Journal of the American Chemical Society, 2006 , vol. 128, # 29 p. 9350 - 9351
反应条件
1: 75 percent / AlCl3 / CH2Cl2 / 12 h / Ambient temperature
2: tetrahydrofuran / 1.) -78 deg C; 2.) up to RT
View Scheme
参考文献
Eisch, John J.; Behrooz, Mohammad; Dua, Suresh K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 121 - 136
反应条件
1: 78 percent / Cu(OAc)2*H2O / pyridine; methanol / 1) 18 h, r.t., 2) 1 h, heating
2: Li / tetrahydrofuran / 1) -10 deg C, 3 h, 2) 0 deg C, 1 h
View Scheme
参考文献
Neugebauer, Wolfgang; Geiger, Gottfried A. P.; Kos, Alexander J.; Stezowski, John J.; Schleyer, Paul von Rague
Chemische Berichte, 1985 , vol. 118, # 4 p. 1504 - 1516
反应条件
1: Li / tetrahydrofuran / 1) -10 deg C, 3 h, 2) 0 deg C, 1 h
View Scheme
参考文献
Neugebauer, Wolfgang; Geiger, Gottfried A. P.; Kos, Alexander J.; Stezowski, John J.; Schleyer, Paul von Rague
Chemische Berichte, 1985 , vol. 118, # 4 p. 1504 - 1516
反应条件
1: 58 percent / EtNiPr2 / diethyl ether / 1) 30 min, 0 deg C 2) 2-5h, room temperature
2: 61 percent / benzene / 4 h / Irradiation
3: benzene / 1 h / 80 °C
View Scheme
参考文献
Schneider, Klaus; Daucher, Birgit; Fronda, Antonio; Maas, Gerhard
Chemische Berichte, 1990 , vol. 123, p. 589 - 594
反应条件
in various solvent(s)
T=160 - 180°C;
参考文献
Maier, Guenther; Born, Dieter; Bauer, Ines; Wolf, Reinhard; Boese, Roland; Cremer, Dieter
Chemische Berichte, 1994 , vol. 127, # 1 p. 173 - 190
反应条件
1: 82 percent Spectr. / 50 °C / Irradiation
2: 1.) aq. sodium hypochlorite / 1.) CHCl3, 25 deg C, 30 min; 2.) 250 deg C
View Scheme
参考文献
Terao, Jun; Kambe, Nobuaki; Sonoda, Noboru
Tetrahedron Letters, 1998 , vol. 39, # 31 p. 5511 - 5512
反应条件
1: 61 percent / benzene / Irradiation
2: 64 percent / benzene / 1.5 h / 80 °C
View Scheme
参考文献
Maas, Gerhard; Schneider, Klaus; Ando, Wataru
Journal of the Chemical Society, Chemical Communications, 1988 , # 1 p. 72 - 74
反应条件
(i) nBuLi, (ii) /BRN= 1209714/, THF; Multistep reaction;
参考文献
Priester,W.; West,R.
Journal of the American Chemical Society, 1976 , vol. 98, p. 8421 - 8425
