顺式-7-氮杂双环[3.3.0]辛烷合成路线 （共 7 条）
反应条件
rhodium contaminated with carbon; hydrogen in tetrahydrofuran T=130°C; P=41254.1 Torr; 11 h; Autoclave; Reagent/catalystTimeTemperaturePressureConcentration;
参考文献
WO2013/102634 A1, ;
Page/Page column 13; 14 ;
反应条件
ammonium formate; palladium on activated charcoal in methanol
参考文献
Roussi, Georges; Zhang, Jidong
Tetrahedron, 1991 , vol. 47, # 28 p. 5161 - 5172
反应条件
1: 1.) NaHCO3; 2.) t-BuOK / 1.) MeOH; 2.) t-BuOH 2: HCOONH4, 10percent Pd-C / methanol View Scheme
参考文献
Tetrahedron Letters, , vol. 29, # 28 p. 3481 - 3482
反应条件
1: 97 percent / Me3SiI / CCl4 2: 1.) NaHCO3; 2.) t-BuOK / 1.) MeOH; 2.) t-BuOH 3: HCOONH4, 10percent Pd-C / methanol View Scheme
参考文献
Tetrahedron Letters, , vol. 29, # 28 p. 3481 - 3482
反应条件
sodium hydroxide; sodium tetrahydroborate; potassium chloride in water T=25°C; pH=12.89; KineticsThermodynamic data; Further Variations:pH-values;
参考文献
Journal of Physical Organic Chemistry, , vol. 15, # 7 p. 363 - 373
反应条件
cis amino chloride in sodium hydroxide T=24.9°C; pH = 13.5; various pH's, concentrations of NH2Cl, temperatures; Kinetics;
参考文献
Delalu, H.; Marchand, A.
Journal de Chimie Physique et de Physico-Chimie Biologique, 1992 , vol. 89, # 6 p. 1413 - 1426
反应条件
cis amino chloride T=25°C; 1.66667 h; influence pH and temperature, machanism; Rate constantThermodynamic dataKinetics;
参考文献
Elkhatib; Marchand; Peyrot; Counioux; Delalu
International Journal of Chemical Kinetics, 1997 , vol. 29, # 2 p. 89 - 98
