氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
[(2,2'-bipyridine)Ni(1,5-cyclooctadiene)] in tetrahydrofuran byproducts: L-leucine oligomers; 16 h stirring; centrifuged, hexane was added, extd. with THF, layered with hexane;
参考文献
Deming, Timothy J.; Curtin, Scott A.
Journal of the American Chemical Society, 2000 , vol. 122, # 24 p. 5710 - 5717
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in further solvent(s) argon-filled glovebox, heating 7.5h at 130°C, cooling to room temp.; gas phase was sampled and analyzed by GC and GC-MS, liquid phase was analyzed by IR;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 6h;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
CH2Cl2 in tetrahydrofuran; dichloromethane KHBpz3 soln. in THF added to stirred soln. equimol. amt. (MeCN)3Mo(CO)3in THF and mixt. stirred for 2 days, slurry Rh(PPh3)3Cl in THF added and mixt. stirred for 2 days; removal of solvent; extn. with C6H6; evapn.; recrystn. from CH2Ch2/hexane; elem. anal.;
参考文献
Banta, Gregory A.; Louie, Brenda M.; Onyiriuka, Emmanuel; Rettig, Steven J.; Storr, Alan
Canadian Journal of Chemistry, 1986 , vol. 64, p. 373 - 386
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, 130°C, 23h; product detd. by GC and IR;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
in dichloromethane FpCH2COFp and RhCl(PPh3)3 are dissolved in CH2Cl2 (Ar), stirring (6h, room temp.).; Filtration of RhCl(PPh3)2(CO), chromy. of filtrate, elem. anal.;
参考文献
Organometallics, , vol. 7, p. 366 - 374
反应条件
carbon oxide sulfide in methanol; dichloromethane addn. of COS-satd. MeOH to soln. of Rh-complex in CH2Cl2, refluxing (3 h, pptn.); filtration, washing (alcohol, ether), drying (vac.); elem. anal.;
参考文献
Inorganica Chimica Acta, , vol. 40, p. 65 - 70
反应条件
in benzene Rh-complex was added to a soln. of Cl3CCOOH in benzene (1:1 ratio), mixt. was stirred at ambient temp. for 3 h under N2; evapd. to dryness under reduced pressure, triturated with Et2O;
参考文献
Boyar, Esther B.; Robinson, Stephen D.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 2113 - 2120
反应条件
hydrogen in 1,2,5-trimethyl-benzene atmosphere of synthesis gas (p(H2+CO)=6 atm), 373 K, 2 min;
参考文献
Ezhova, N. N.; Korneeva, G. A.; Kurkin, V. I.; Filatova, M. P.; Slivinsky, E. V.
Russian Chemical Bulletin, 1995 , vol. 44, # 5 p. 836 - 839
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 5 p. 863 - 866
