氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
hydrogen in 1,2,5-trimethyl-benzene Kinetics; solvent: mesitylene with N,N-dimethylacetamide (80/20, w/w), atmosphere:synthesis gas (p(H2+CO)=6 atm), 373 K, 2 min;
参考文献
Ezhova, N. N.; Korneeva, G. A.; Kurkin, V. I.; Filatova, M. P.; Slivinsky, E. V.
Russian Chemical Bulletin, 1995 , vol. 44, # 5 p. 836 - 839
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 5 p. 863 - 866
反应条件
80°C, excess benzoyl chloride, 15 min;
参考文献
Journal of the American Chemical Society, , vol. 103, p. 1847 - 1849
反应条件
Kinetics; 80°C, excess benzoyl chloride, 24-96 h; sepn. by chromy. (silica gel, CH2Cl2); RhClCO(PPh3)2 is only a minor product; elem. anal.;
参考文献
Kampmeier, J. A.; Rodehorst, R. M.; Philip, J. B.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1847 - 1849
反应条件
in tetrahydrofuran N2-atmosphere; stirring overnight; evapn., chromy. (Al2O3, toluene/CH2Cl2=5:1);
参考文献
Inorganica Chimica Acta, , vol. 38, p. 243 - 246
反应条件
in benzene byproducts: triphenylphosphine; to suspn. of Rh complex in C6H6 added HCOF at room temp. under N2, stirred for 1 h; filtered, washed with pentane; elem. anal.;
参考文献
Doyle, Gerald
Journal of Organometallic Chemistry, 1982 , vol. 224, # 4 p. 355 - 362
反应条件
in benzene to suspn. of Rh complex in C6H6 added dropwise soln. of CH3COOC(O)H in C6H6 at room temp. under N2, stirred for 2 h; filtered, washed with pentane, dried;
参考文献
Doyle, Gerald
Journal of Organometallic Chemistry, 1982 , vol. 224, # 4 p. 355 - 362
反应条件
in tetrahydrofuran N2-atmosphere; stirring overnight; evapn., chromy. (Al2O3, toluene/CH2Cl2=5:1);
参考文献
Inorganica Chimica Acta, , vol. 38, p. 243 - 246
反应条件
in tetrahydrofuran N2-atmosphere; refluxing hexacarbonyl with LiCp(*) for 50 h, addn. to Rh-complex, stirring at room temp. for 1 h; water addn., decantation, collection (filtration), washing (water), drying (vac.), extn. into CH2Cl2, filtration, evapn., dissoln. in CH2Cl2, crystn. on layering with pentane (room temp., 3 d), washing (petroleum ether), drying (vac.); elem. anal.;
参考文献
Lindsell, W. Edward; McCullough, Kevin J.; Plancq, Sabine
Journal of Organometallic Chemistry, 1995 , vol. 491, # 1-2 p. 275 - 282
反应条件
in further solvent(s) argon-filled glovebox, 1 equiv. of RhCl(PPh3)3 was heated 2-12h at 130-140°C, other solvent; detd. spect.;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
in ethanol refluxing;
参考文献
Teixidor; Flores; Vinas; Kivekas; Sillanpaa
Angewandte Chemie - International Edition in English, 1996 , vol. 35, # 19 p. 2251 - 2253
