氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
in methanol; dichloromethane Irradiation (UV/VIS); addn. of methanolic soln. of COS to a soln. of Rh(I) complex and P(C6H5)3 in CH2Cl2; filling up with methanol; irradiation (at about 250nm), 30min, stirring; crystn.; react. mechanism discussed;; filtration; washing (CH3OH/ether); drying; concn. of reddish brown filtrate in a flash evaporator at 75°C, reduced pressure; cooling of deep brown soln.; filtration; washing residue with ether; dissoln. in CH2Cl2; repptn.; drying; elem. anal.;;
参考文献
Datta, Someswar; Agarwala, U. C.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1981 , vol. 20, # 12 p. 1153 - 1155
反应条件
2,2,6,6-tetramethylpiperine in further solvent(s) argon-filled glovebox, bibenzyl, 130°C, 28h, further products; product detd. by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in N,N-dimethyl acetamide argon-filled glovebox, durene, bibenzyl, heating 23h, further products; detn. of products by GC;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
in N,N-dimethyl acetamide argon-filled glovebox, durene, bibenzyl, heating 23h, further products; detn. of products by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in not given byproducts: CO;
参考文献
Akita, Munetaka; Andoh, Hitoshi; Mitani, Osamu; Oku, Tomoharu; Moro-Oka, Yoshihiko
Journal of Molecular Catalysis, 1989 , vol. 56, p. 107 - 116
反应条件
in N,N-dimethyl acetamide argon-filled glovebox, durene, bibenzyl, heating 23h, further products; detn. of products by GC;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
catalyst: HCl in further solvent(s) argon-filled glovebox, bibenzyl, 130°C, 30min.; product detd. by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 6h;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
in further solvent(s) argon-filled glovebox, 1 equiv. of RhCl(PPh3)3 was heated 2-12h at 130-140°C, other solvent; detd. spect.;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
