氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
in further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 6h;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
2,2,6,6-tetramethylpiperine in further solvent(s) argon-filled glovebox, bibenzyl, 130°C, 28h, further products; product detd. by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
2,2,6,6-tetramethylpiperine in further solvent(s) argon-filled glovebox, bibenzyl, 130°C, 28h, further products; product detd. by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in N,N-dimethyl acetamide argon-filled glovebox, durene, bibenzyl, heating 23h, further products; detn. of products by GC;
参考文献
Organometallics, , vol. 8, p. 2703 - 2708
反应条件
in dichloromethane-d2 byproducts: H2, P(C6H5)3; dropwise addn. of soln. of catecholborane to soln. of Rh-complex; not isolated; (1)H-, (11)B- and (31)P-NMR spectroscopy; further products;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in THF-d8 (tetrahydrofuran-d8) byproducts: P(C6H5)3; addn. of soln. of catecholborane to soln. of Rh-complex and oct-1-ene (-78°C, NMR tube), warming (-40°C, (31)P-NMR monitoring), warming to 25°C; (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in benzene Kinetics; N2-atmosphere; chromy. (Al2O3);
参考文献
Kuhlmann, Erven J.; Alexander, John J.
Inorganica Chimica Acta, 1979 , vol. 34, p. 197 - 210
反应条件
in dichloromethane to the complex and phosphenium CDCl3 was added at room temp.; not sepd., detected by NMR spectra;
参考文献
Abrams, Michael B.; Scott, Brian L.; Baker, R. Thomas
Organometallics, 2000 , vol. 19, # 24 p. 4944 - 4956
反应条件
in dichloromethane N2-atmosphere; equimolar amts., stirring (3 h); cooling, filtration off of Rh-complex, solvent removal (reduced pressure), chromy. (alumina);
参考文献
Kuhlmann, Erven J.; Alexander, John J.
Inorganica Chimica Acta, 1979 , vol. 34, p. 197 - 210
反应条件
hydrogen in 1,2,5-trimethyl-benzene Kinetics; solvent: mesitylene with N,N-dimethylacetamide (80/20, w/w), atmosphere:synthesis gas (p(H2+CO)=6 atm), 373 K, 2 min;
参考文献
Ezhova, N. N.; Korneeva, G. A.; Kurkin, V. I.; Filatova, M. P.; Slivinsky, E. V.
Russian Chemical Bulletin, 1995 , vol. 44, # 5 p. 836 - 839
Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1995 , # 5 p. 863 - 866
