氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
in deuterated toluene at 210 K; not isolated; detd. by (14)P NMR;
参考文献
Jackson, Sarah M.; Chisholm, Danielle M.; McIndoe, J. Scott; Rosenberg, Lisa
European Journal of Inorganic Chemistry, 2011 , # 3 p. 327 - 330
反应条件
2,2,6,6-tetramethylpiperine in further solvent(s) argon-filled glovebox, bibenzyl, 130°C, 28h, further products; product detd. by GC;
参考文献
Andrews, Mark A.
Organometallics, 1989 , vol. 8, p. 2703 - 2708
反应条件
in dichloromethane equilibrium react.;
参考文献
Mitchell, R. W.; Ruddick, J. D.; Wilkinson, G.
Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1971 , p. 3224 - 3230
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Gmelin Handbook: Rh: SVol.B3, 4.24.3.3, page 133 - 134
反应条件
alkene Kinetics; byproducts: RhCl(alkene)(PPh3)2;
参考文献
Ohtani, J.; Fujimoto, M.; Yamagishi, A.
Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 1453 - 1459
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Gmelin Handbook: Rh: SVol.B3, 4.24.3.3, page 133 - 134
反应条件
in dichloromethane 1.5 h; Heating; MechanismProduct distribution;
参考文献
Journal of Organic Chemistry, , vol. 45, # 2 p. 315 - 318
反应条件
80°C, excess benzoyl chloride, 15 min;
参考文献
Journal of the American Chemical Society, , vol. 103, p. 1847 - 1849
反应条件
Kinetics; 80°C, excess benzoyl chloride, 24-96 h; sepn. by chromy. (silica gel, CH2Cl2); RhClCO(PPh3)2 is only a minor product; elem. anal.;
参考文献
Kampmeier, J. A.; Rodehorst, R. M.; Philip, J. B.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1847 - 1849
反应条件
in not given
catalyzed hydroboration of CH(C6H4O2B)CH(C6H4OCH3) using RhClPPh3 and HBcat under dry N2; monitoring by NMR and GC/MAS;
参考文献
Baker, R. Thomas; Calabrese, Joseph C.; Westcott, Stephen A.; Nguyen, Paul; Marder, Todd B.
Journal of the American Chemical Society, 1993 , vol. 115, # 10 p. 4367 - 4368
反应条件
in THF-d8 (tetrahydrofuran-d8)
byproducts: P(C6H5)3; addn. of soln. of catecholborane to soln. of Rh-complex and oct-1-ene (-78°C, NMR tube), warming (-40°C, (31)P-NMR monitoring), warming to 25°C; (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in tetrahydrofuran
under N2, 0°C, 5-10 min.; filtration, reduction of vol., addn. of large vol. of cold petroleum;
参考文献
Irvine, Derek J.; Glidewell, Christopher; Cole-Hamilton, David J.; Barnes, John C.; Howie, Alan
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , # 7 p. 1765 - 1772
