in gaseous matrix
Kinetics; byproducts: PH2; (Ar); react. of Cl atoms (generated by microwave discharge of Cl2) andPH3 at room temp. in an Ar flow at 0.7 torr within ca. 0.3 ms; not isolated, detected by IR chemiluminescence;
参考文献
Wickramaaratchi, M. A.; Setser, D. W.
Journal of Physical Chemistry, 1983 , vol. 87, # 1 p. 64 - 72
in gaseous matrix
Kinetics; byproducts: GeH3; (Ar); react. of Cl atoms (generated by microwave discharge of Cl2) andGeH4 at room temp. in an Ar flow at 0.7 torr within ca. 0.3 ms; not isolated, detected by IR chemiluminescence;
参考文献
Wickramaaratchi, M. A.; Setser, D. W.
Journal of Physical Chemistry, 1983 , vol. 87, # 1 p. 64 - 72
in gas
Kinetics; byproducts: ClNO2; Irradiation (UV/VIS); the reaction mixt. contg. 0.2-1.5 Torr of Cl2, 0.6-2.5 Torr of HNO3, and 80 Torr of He is photolyzed by pulsed laser light (351 nm); products not isolated, reaction studied by time-resolved long-path laser absorption technique;
参考文献
Wine, P. H.; Wells, J. R.; Nicovich, J. M.
Journal of Physical Chemistry, 1988 , vol. 92, # 8 p. 2223 - 2228