(-)-1,2-双[(2R,5R)-2,5-二甲基磷]苯合成路线 （共 5 条）
反应条件
cupric triflate; 1,1,3,3-tetramethyldisiloxane in toluene T=100°C; Inert atmosphere;
参考文献
Li, Yuehui; Das, Shoubhik; Zhou, Shaolin; Junge, Kathrin; Beller, Matthias
Journal of the American Chemical Society, 2012 , vol. 134, # 23 p. 9727 - 9732
反应条件
1: 1.) SOCl2, 2.) RuCl3*3H2O, NaIO4 / 1.) CCl4, reflux, 1.5 h, 2.) CCl4, CH3CN, H2O, 25 deg C, 1 h 2: 1.) n-BuLi, 3.) n-BuLi View Scheme
参考文献
Journal of the American Chemical Society, , vol. 115, # 22 p. 10125 - 10138
参考文献
Journal of the American Chemical Society, , vol. 113, # 22 p. 8518 - 8519
反应条件
1: BH3*DMS / tetrahydrofuran / 0.75 h / 0 °C
2: aq. H2O2 / tetrahydrofuran / 0.75 h / 20 °C
3: 477 mg / DABCO(TM) / benzene / 5 h / 50 °C
View Scheme
参考文献
Boezio, Alessandro A.; Pytkowicz, Julien; Cote, Alexandre; Charette, Andre B.
Journal of the American Chemical Society, 2003 , vol. 125, # 47 p. 14260 - 14261
反应条件
diethylzinc; copper(II) bis(trifluoromethanesulfonate) in toluene
T=20°C; 0.5 h; Product distribution; Further Variations:Reagents;
参考文献
Cote, Alexandre; Boezio, Alessandro A.; Charette, Andre B.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 47 p. 6525 - 6528
