二氯(1,10-亚铁试剂)钯(II)合成路线 （共 30 条）
反应条件
in hydrogenchloride; ethanol addn. of ethanolic soln. of 1,10-phenanthroline to soln. of K2PdCl4 in aq. HCl with stirring, boiled for 2 h; washed with water, ethanol, acetone and diethyl ether, dried at 100°C; elem. anal.;
参考文献
Fox, S. G.; Gillard, R. D.
Polyhedron, 1988 , vol. 7, p. 349 - 352
反应条件
hydrogenchloride in ethanol; water addn. of concd. HCl to an aq. PdCl2 soln., filtration of the soln. and addn. of a soln of 1,10-phenanthroloine*H2O in ethanol to the filtered soln.; stirring for 2 h, filtering the ppt., washing with ethanol and drying in vacuo, elem. anal.;
参考文献
Shiotani; Itatani; Inagaki
Journal of molecular catalysis, 1986 , vol. 34, # 1 p. 57 - 66
反应条件
HCl in water Electrochem. Process; electrolysis of Pd-foil at 3 V for 60 min; HCl containing phenanthroline as electrolyte; filtn., elem. anal.;
参考文献
Chakravorti, M. C.; Subrahmanyam, Gampa V. B.
Polyhedron, 1992 , vol. 11, p. 3191 - 3196
反应条件
in dichloromethane byproducts: 2-I-C6H4CH2C(CH3)2NH2; ligand added to a suspn. of Pd complex, stirred for 4 h; filtered;
参考文献
Vicente, Jose; Saura-Llamas, Isabel; Bautista, Delia
Organometallics, 2005 , vol. 24, # 24 p. 6001 - 6004
反应条件
in dichloromethane byproducts: (S)-2-I-C8H5N-CH2CH(CO2CH3)NH2; ligand added to a soln. of Pd complex, stirred for 4 h; filtered;
参考文献
Vicente, Jose; Saura-Llamas, Isabel; Bautista, Delia
Organometallics, 2005 , vol. 24, # 24 p. 6001 - 6004
反应条件
in dimethyl sulfoxide 100°C, 10 min; monitored by (1)H NMR;
参考文献
Jung, Miso; Suzaki, Yuji; Saito, Takashi; Shimada, Kyoichi; Osakada, Kohtaro
Polyhedron, 2012 , vol. 40, # 1 p. 168 - 174
反应条件
in water stirring Na2PdCl4 with 1 equiv. ligand and excess HCl (80°C, 30 min); standing at room temp. for several h, collection (filtration), washing (water, MeOH); elem. anal.;
参考文献
Okamoto, Ken-Ichi; Yoshinari, Yukie; Yamada, Yasunori; Sakagami, Narumi; Konno, Takumi
Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 6 p. 1363 - 1371
反应条件
in acetonitrile addn. of soln. of ligand to hot soln. of PdCl2; pptn. on cooling. filtration off, washing (acetonitrile, acetone), drying (vac.);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 403 - 412
反应条件
C6H5I(OCOCH3)2 in dichloromethane byproducts: (R)-2-methoxy-C6H4CH(NH2)COOCH3; addn. of PhI(OAc)2 to a suspn. of Pd complex in methanol, stirring for 20 h at room temp., filtration, evapn., dissolving in CH2Cl2, washing with Na2SO3, drying org. phase over MgSO4, filtration, addn. of phenanthroline hydrate, stirring for 3 h; filtration;
参考文献
Inorganic Chemistry, , vol. 48, # 24 p. 11963 - 11975
反应条件
C6H5I(OCOCH3)2 in dichloromethane byproducts: (R)-2-ethoxy-C6H4CH(NH2)COOCH3; addn. of PhI(OAc)2 to a suspn. of Pd complex in ethanol, stirring for 20h at room temp., filtration, evapn., dissolving in CH2Cl2, washing with Na2SO3, drying org. phase over MgSO4, filtration, addn. of phenanthroli ne hydrate, stirring for 3 h; filtration;
参考文献
Inorganic Chemistry, , vol. 48, # 24 p. 11963 - 11975
