4-溴-2,6-二甲基苯甲醚合成路线 （共 24 条）
反应条件
kaolin; sodium chlorite; Mn(III) acetylacetonate; sodium bromide in dichloromethane T=25°C; 1 h;
参考文献
Hirano, Masao; Monobe, Hiroyuki; Yakabe, Shigetaka; Morimoto, Takashi
Journal of Chemical Research - Part S, 1998 , # 10 p. 662 - 663
反应条件
sodium hydroxide; tetra-(n-butyl)ammonium iodide in dichloromethane; water
参考文献
Morimoto, Toshiaki; Chiba, Mitsuo; Achiwa, Kazuo
Tetrahedron Letters, 1989 , vol. 30, # 6 p. 735 - 738
反应条件
1: 4-bromo-2,6-dimethyl-phenol With sodium hydride in dimethyl sulfoxide T=0°C; 0.916667 h; Inert atmosphere; 2: methyl iodide in dimethyl sulfoxide T=0 - 20°C; 5.66667 h; Inert atmosphere;
参考文献
Sookcharoenpinyo, Bunyarithi; Klein, Emmanuel; Ferrand, Yann; Walker, D. Barney; Brotherhood, Peter R.; Ke, Chenfeng; Crump, Matthew P.; Davis, Anthony P.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 19 p. 4586 - 4590
反应条件
sulfuric acid; sodium nitrite Eintragen der Reaktionsloesung in siedende wss. HBr unter Zusatz von Cu2O;
参考文献
Journal of Organic Chemistry, , vol. 18, p. 83,87
反应条件
1: ethanolic sodium ethylate 2: Raney nickel; diethyl ether / Hydrogenation 3: aqueous H2SO4; NaNO2 / Eintragen der Reaktionsloesung in siedende wss. HBr unter Zusatz von Cu2O View Scheme
参考文献
Journal of Organic Chemistry, , vol. 18, p. 83,87
反应条件
1: Raney nickel; diethyl ether / Hydrogenation 2: aqueous H2SO4; NaNO2 / Eintragen der Reaktionsloesung in siedende wss. HBr unter Zusatz von Cu2O View Scheme
参考文献
Journal of Organic Chemistry, , vol. 18, p. 83,87
反应条件
2: bromine View Scheme
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 42, p. 211 - 222
反应条件
2: platinum; ethanol / Hydrogenolyse 3: glacial acetic acid 4: platinum; ethanol / Hydrogenolyse View Scheme
参考文献
Bulletin de la Societe Chimique de France, , vol. <5> 6, p. 1025,1033
反应条件
1: glacial acetic acid 2: platinum; ethanol / Hydrogenolyse View Scheme
参考文献
Bulletin de la Societe Chimique de France, , vol. <5> 6, p. 1025,1033
