反应条件
sodium perchlorate; [Ru(tris(2,2'-bipyridyl))3]Cl2·6H2O in water
Kinetics; Irradiation (UV/VIS); aq. soln. contg. 5E-5 M Ru complex, 0.004 M Na2C2O4, 0.5 M NaClO4, satd. with N2, irradiated at 30°C with 100-W W lamp; sample of soln. treated with cation-exchange resin Dowex 50W-X8 (H(1+) form), filtered, concn. of S2O8(2-) determined by polarography;
参考文献
Kimura, Masaru; Nishida, Suzuko
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1985 , p. 355 - 360