2-ethyl-2-hydroxybutyric acid in water
Kinetics; react. of Cr(V)-compd. and sulfite is carried out in a buffered aq. soln., containing 2-ethyl-2-hydroxybutyric acid and its sodium salt (pH=3.4), HSO3(1-) taken in excess.; UV;
参考文献
Bose, Rathindra N.; Rajasekar, N.; Thompson, Dorena M.; Gould, E. S.
Inorganic Chemistry, 1986 , vol. 25, p. 3349 - 3353
water in water
Kinetics; solns. of NaOCl and Na2SO3 (both adjusted to pH 8) mixed in presence of phenolphthalein (indicator); color change via pink to colorless; kinetics of hydrolysis of ClSO3(1-) (intermediate) detd.; react. mechanism discussed;
