water in water
Kinetics; solns. of NaOCl and Na2SO3 (both adjusted to pH 4) mixed in presence of 2,4-dinitrophenol (indicator); decrease of yellow color; hydrolysis of ClSO3(1-) (intermediate) at different temps. spect. at 410 nm detd.; react. mechanism discussed;
Na2O2 in not given
heating with large excess of Na2O2;;
参考文献
Macbeth, A. K.; Graham, H.
Proceedings of the Royal Irish Academy, Section B: Biological, Geological and Chemical Science, 1921 , vol. 36, p. 31 - 40
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Gmelin Handbook: S: MVol.B3, 13, page 1556 - 1558
1.0-12.5percent RuO2/WO3 catalyst in water
Kinetics; byproducts: O2; Irradiation (UV/VIS); decompn. of peroxomonosulfate ion on photolysis (250-W high-pressure Hg lamp., λ>=410 nm) in presence of catalyst dispersion; iodometric estimation of concn. of HSO5(1-), anal. of evolved O2;
参考文献
Maruthamuthu, Pichai; Ashokkumar, Muthupandian; Venkatasubramanian, Lakshmanan
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 11 p. 4137 - 4142
