perchloric acid in water
Kinetics; Irradiation (UV/VIS); further intermediate: ClOH(1-); K2S2O8 and NaCl dissolved in water; pH adjusted by HClO4; solution photolyzed at 248 nm; at 297 K;
参考文献
Yu, Xiao-Ying; Bao, Zhen-Chuan; Barker, John R.
Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment, & General Theory, 2004 , vol. 108, # 2 p. 295 - 308
sodium hydroxide; water in tetrachloromethane
Kinetics; Irradiation (UV/VIS); hydrolysis in daylight (or artificial light); aq. NaOH; shaking; mechanism and presence of CdCO3 discussed; dependence on temp. and concn. of NaOH discussed;; monitored by UV spectroscopy;;
参考文献
Rao, M. R. A.
Proceedings - Indian Academy of Sciences, Section A, 1940 , vol. 11, p. 201 - 205
Brit. C.A., 1940 , p. I 296
water in water
long heating of alkaline earth thiosulfates;
参考文献
Orlowski, A.
Zeitschrift fuer Analytische Chemie, 1883 , vol. 22, p. 357 - 366
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Gmelin Handbook: S: MVol.B2, 7.3.2, page 874 - 876
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反应条件
in not given
in 0.01m S2O3(2-) soln.;
参考文献
Bassett, H.; Durrant, R. G.
Journal of the Chemical Society, 1923 , vol. 123, p. 1279 - 1291
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Vortmann, G.
Monatshefte fuer Chemie, 1888 , vol. 9, p. 165 - 179
sulfur dioxide in perchloric acid
Kinetics; byproducts: V(IV); various temp., in HClO4 acid medium (< 0.4 M ), addn. of a known volume of sulphite to an aq. soln. alredy containing other reactants; not isolated, detected by IR and UV;
参考文献
Gupta, Kalyan Kali Sen; Das, Sankar; Gupta, Shipra Sen
Journal of Chemical Research, Synopses, 1989 , p. 112 - 113