TiO2#dotPt, anatase in water
Irradiation (UV/VIS); 1E-3 M aq. soln. of Na2SO3 and doped TiO2 stirred with bubbling O2, illuminated with ultrahigh-pressure Hg lamp (500 W) through cutoff filter (50percent transmittance at 290 nm, 0percent one at <240 nm) for 1 h;
参考文献
Matsumoto, Yasumichi; Yamaguchi, Yasuhide; Sato, Ei-ichi
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 4 p. 1255 - 1258
sodium acetate; acetic acid in water
Kinetics; oxidation of sulfite by chlorine dioxide investigated in slightly acidicmedium between pH 3.65 and 4.55 at 25°C; sulfite excess used; not isolated;
参考文献
Horvath, Attila K.; Nagypal, Istvan
Journal of Physical Chemistry A, 2006 , vol. 110, # 14 p. 4753 - 4758
sodium hydroxide; water in Petroleum ether
byproducts: polythionic acids; alkaline hydrolsis; shaking (2 h) of SCl2 (in petroleum ether) mixed with water (free of air) in presence of NaOH; yields depending on acidity discussed;;
参考文献
Goehring, M.; Stamm, H.; Feldmann, U.
Z. Anorg. Chem., 1942 , vol. 250, p. 56 - 71
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Gmelin Handbook: S: MVol.B3, 119, page 1786 - 1788
Charlot, G.
Bulletin de la Societe Chimique de France, 1943 , vol. 10, p. 343 - 347
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Gmelin Handbook: S: MVol.B2, 6, page 808 - 852
sodium hydroxide; water in tetrachloromethane
Kinetics; byproducts: iodide; hydrolysis in darkness; aq. NaOH; shaking; mechanism and presence of CdCO3 discussed; dependence on temp. and concn. of NaOH discussed;; monitored by UV spectroscopy;;
参考文献
Rao, M. R. A.
Proceedings - Indian Academy of Sciences, Section A, 1940 , vol. 11, p. 201 - 205
Brit. C.A., 1940 , p. I 296