sodium hydroxide; water in tetrachloromethane
byproducts: CdS; equilibrium of decompn. and hydrolysis discussed; aq. NaOH, presence of Cd(OH)2; presence of I2 discussed;;
参考文献
Rao, M. R. A. N.
Current Science, 1937 , vol. 6, p. 63 - 63
Full Text Show Details
Rao, M. R. A. N.
J. Mysore Univ., 1940 , # I p. 75 - 82
C. A., 1941 , p. 6527
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反应条件
potassium hydroxide in water
total decompn. by alkaline H2O2 (10percent KOH);;
sodium nitrate; acetate buffer; water in water
Kinetics; byproducts: Co(aq)(2+), NH4(1+), NH3; mixing of aq. sulfite and molybdatopentaamminecobalt(III) in CH3COOH-CH3COONa buffer (4.47 <pH < 5.12) at 24.9-37.6°C, adjusting of ionic strength with NaNO3; monitoring by UV;
参考文献
Holder, Alvin A.; Dasgupta, Tara P.
Inorganica Chimica Acta, 2002 , vol. 331, # 1 p. 279 - 289
KMnO4 or Ce(SO4)2 in water
byproducts: polythiocyanogen, H(1+);
参考文献
Vorob'ev-Desyatovskii, N. V.; Usman, M. Sheikh; Sokolov, V. V.; Kukushkin, Yu. N.
Journal of General Chemistry USSR (English Translation), 1991 , vol. 61, p. 2067 - 2072
Zhurnal Obshchei Khimii, 1991 , vol. 61, p. 2227 - 2233
(ethylenedinitrilo)tetraacetic acid disodium salt in water
Kinetics; dissolving of thiosulfate in H2O (purging with N2), varying pH, ionic strength (NaClO4 or KNO3), addn. of Co-complex at 25 or 60°C; monitoring by UV;
参考文献
Ali, Mahammad; Saha, Swapan K.; Banerjee, Pradyot
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2497 - 2501
→
反应条件
(ethylenedinitrilo)tetraacetic acid disodium salt in water
Kinetics; dissolving of thiosulfate in H2O (purging with N2), varying pH, ionic strength (NaClO4 or KNO3), addn. of Co-complex at 25 or 60°C; monitoring by UV;
参考文献
Ali, Mahammad; Saha, Swapan K.; Banerjee, Pradyot
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2497 - 2501
Vorob'ev-Desyatovskii, N. V.; Usman, M. Sheikh; Sokolov, V. V.; Kukushkin, Yu. N.
Journal of General Chemistry USSR (English Translation), 1991 , vol. 61, p. 2067 - 2072
Zhurnal Obshchei Khimii, 1991 , vol. 61, p. 2227 - 2233
Ce(SO4)2 or KMnO4 in water
byproducts: polythiocyanogen, H(1+);
参考文献
Vorob'ev-Desyatovskii, N. V.; Usman, M. Sheikh; Sokolov, V. V.; Kukushkin, Yu. N.
Journal of General Chemistry USSR (English Translation), 1991 , vol. 61, p. 2067 - 2072
Zhurnal Obshchei Khimii, 1991 , vol. 61, p. 2227 - 2233
Vorob'ev-Desyatovskii, N. V.; Usman, M. Sheikh; Sokolov, V. V.; Kukushkin, Yu. N.
Journal of General Chemistry USSR (English Translation), 1991 , vol. 61, p. 2067 - 2072
Zhurnal Obshchei Khimii, 1991 , vol. 61, p. 2227 - 2233
Ce(SO4)2 or KMnO4 in water
byproducts: polythiocyanogen, H(1+); compd. is oxidized very slowly even at 90°C;
参考文献
Vorob'ev-Desyatovskii, N. V.; Usman, M. Sheikh; Sokolov, V. V.; Kukushkin, Yu. N.
Journal of General Chemistry USSR (English Translation), 1991 , vol. 61, p. 2067 - 2072
Zhurnal Obshchei Khimii, 1991 , vol. 61, p. 2227 - 2233
