in water
Kinetics; oxidation of HSO3(1-) by HSO5(1-) (25°C +/-0.2°C, ionic strength = 0.0050 M, pH = 2.25 - 7.87, formate or succinate buffer); not isolated; UV/VIS monitoring;
参考文献
Connik, Robert E.; Lee, Shaoyung; Adamic, Raymond
Inorganic Chemistry, 1993 , vol. 32, p. 565 - 571
sodium acetate; acetic acid in water
Kinetics; iodine and tetrathionate reacted at 25.0.+-.0.1 °C and at an ionic strength of 0.5 M adjusted by sodium acetate as a buffer component both the absence and presence of the iodide ion in the pH range of 4.25-5.55; not isolated;
参考文献
Kerek, Attila; Horvath, Attila K.
Journal of Physical Chemistry A, 2007 , vol. 111, # 20 p. 4235 - 4241
TiO2#dotPt, anatase in water
Irradiation (UV/VIS); 1E-3 M aq. soln. of Na2S2O3 and doped TiO2 stirred with bubbling O2, illuminated with ultrahigh-pressure Hg lamp (500 W) through cutoff filter (50percent transmittance at 290 nm, 0percent one at <240 nm) for 1 h;
参考文献
Matsumoto, Yasumichi; Yamaguchi, Yasuhide; Sato, Ei-ichi
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 4 p. 1255 - 1258
Marschall
Journal of the Chemical Society, 1891 , vol. 59, # I p. 771 - 771
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Gmelin Handbook: S: MVol.B2, 6, page 808 - 852
hydrogen cation in perchloric acid
Kinetics; byproducts: H2O; react. of excess bromate with sulfide in aq. HClO4 (ionic strength: 0.2 M (NaClO4)) at 22°C, Br2 appeared after induction period; SO4(2-) detected with Ba(2+);
参考文献
Simoyi, Reuben H.; Noyes, Richard M.
Journal of Physical Chemistry, 1987 , vol. 91, # 11 p. 2689 - 2690
