water in water
Kinetics; byproducts: H(1+); pH 1-9, ionic strength 0.2 M (NaClO4), 25.0+/-0.1 °C; spectrophotometric (474 nm), potentiometric and pH-metric monitoring;
in further solvent(s)
byproducts: H(1+); warming 10 min;
参考文献
Sander, A.
Chemiker-Zeitung, 1915 , vol. 39, p. 945 - 947
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Gmelin Handbook: S: MVol.B2, 7.5.1, page 903 - 907
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Kurtenacker, A.
Analytische Chemie der Sauerstoffsaeure des Schwefels, Stuttgart 1938, p. 118
water in water
byproducts: polythionic acids; storage for longer period of time (room temp./CO2 atm./exclusion of air/75 or 500 fold excess of water); reaction discussed;;
参考文献
Noack, E.
Z. Anorg. Chem., 1925 , vol. 146, p. 239 - 262
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
sodium hydroxide; water; cadmium (II) chloride in tetrachloromethane
byproducts: CdS; alkaline hydrolysis; shaking (1-2 min) of S2Cl2 (10E4 -10E3 mol/in CCl4) with excess aq. NaOH (very dild.) in presence of CdCl2; further byproduct: Sμ; mechanism (depending on concns. of educts and temps.) discussed;;
参考文献
Rao, B. S.
Proceedings - Indian Academy of Sciences, Section A, 1939 , vol. 10, p. 423 - 448
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Gmelin Handbook: S: MVol.B3, 112, page 1770 - 1773
aluminum oxide in neat (no solvent)
gas flow containing H2S and O2 over Al2O3 catalyst (303, 343 or 453 K); sepn. of products by GC;
参考文献
Ziolek, Maria; Kujawa, Jolanta; Mohammed Saad, Abdel Basset; Saur, Odette; Lavalley, Jean-Claude
Bulletin de la Societe Chimique de France, 1987 , p. 37 - 41
