in water
Kinetics; S2O8(2-) excess, 298.2+/-0.1 K; monitoring by UV spectroscopy at 522 nm;
参考文献
Matamoros-Fontenla; Perez; Lopez; Prado-Gotor; De La Vega; Sanchez
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1997 , vol. 101, # 10 p. 1452 - 1460
in acetonitrile
purging soln. of Ni-complex with SO2, then stirring under 1 atm O2 for 24 h (pptn.); filtration off of Ni-complex, detn. of SO4(2-) in filtrate by pptn. with BaCl2;
参考文献
Darensbourg, Marcetta Y.; Tuntulani, Thawatchai; Reibenspies, Joseph H.
Inorganic Chemistry, 1995 , vol. 34, p. 6287 - 6294
in acetonitrile
purging soln. of Ni-complex with SO2, then stirring under 1 atm O2 for 24 h (pptn.); filtration off of Ni-complex, detn. of SO4(2-) in filtrate by pptn. with BaCl2;
参考文献
Darensbourg, Marcetta Y.; Tuntulani, Thawatchai; Reibenspies, Joseph H.
Inorganic Chemistry, 1995 , vol. 34, p. 6287 - 6294
→
反应条件
in water
byproducts: Cl(1-); Mo complex dissolved in H2O; aq. soln. of Na2SO3 added; not isolated; detd. by UV-vis spectroscopy and ion chromy.;
参考文献
Wallace, Dawn; Gibson, Lorraine T.; Reglinski, John; Spicer, Mark D.
Inorganic Chemistry, 2007 , vol. 46, # 10 p. 3804 - 3806
