1.1: potassium phosphate; tetrakis(triphenylphosphine) palladium(0) / ethanol / 6 h / |Reflux; |Inert atmosphere 2.1: hydrazine hydrate / methanol / 2 h / 20 °C 3.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / |Cooling with ice 3.2: 20 °C / |Cooling with ice 4.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 5.1: copper(l) iodide; copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / |Inert atmosphere View Scheme

1.1: hydrazine hydrate / methanol / 2 h / 20 °C 2.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / |Cooling with ice 2.2: 20 °C / |Cooling with ice 3.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 4.1: copper(l) iodide; copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / |Inert atmosphere View Scheme

1.1: hydrogenchloride; sodium nitrite / tetrahydrofuran; water / 0.33 h / |Cooling with ice 1.2: 20 °C / |Cooling with ice 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 3.1: copper(l) iodide; copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / |Inert atmosphere View Scheme

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 20 °C 2: copper(l) iodide; copper diacetate; sodium carbonate; ethylene glycol / isopropyl alcohol / 16 h / 85 °C / |Inert atmosphere View Scheme

暂无反应条件数据

AlCl3, aluminium chloride in dichloromethane T=0 - 20°C;

zinc(II) chloride in dichloromethane T=20°C; 24 h;

1: With tin(IV) chloride in dichloromethane T=20°C; 24 h; 2: With hydrogenchloride in dichloromethane; water Cooling with ice;

1: N,N-dimethyl-formamide With trichlorophosphate in N,N-dimethyl-formamide T=0 - 20°C; Vilsmeier-Haack Formylation; 1 h; Inert atmosphere; 2: N-(n-butyl)carbazole in N,N-dimethyl-formamide T=100°C; Vilsmeier-Haack Formylation; 1 h; Inert atmosphereMicrowave irradiation;

trichlorophosphate in N,N-dimethyl-formamide T=20 - 60°C; 9 h;