C51H60O11P2; hydrogen; Rh nonanoate in toluene T=120°C; P=15001.5 Torr; 3 h; Inert atmosphere; Product distribution / selectivity;

[rhodium(I)(carbonyl)2(acetylacetonate)]; C72H46F24P4; hydrogen in toluene T=125°C; P=3800.26 Torr; 2 h; Autoclave; regioselective reaction;

in hexane; benzene a mixt. of Cp2ZrHCl and 3-octene in benzene was stirred for ca. 2 h at room temp. under N2, a soln. of anhyd. SnCl4 in n-hexane was added dropwise (Cp2ZrHCl/SnCl4 ratio 2:1), stirred for a further 1 h 30 min; hexane was added, ppt. of Cp2ZrCl2 was filtered off, filtrate was concd., residue extd. with hexane, exts. were combined, concd., dild. with methanol; (octyl)SnCl3 content was detd. by titrn. with 0.02 M EDTA;

bis(1,5-cyclooctadiene)nickel (0); tris(n-hexyl)aluminium in n-heptane T=80°C; 2 h; Product distribution / selectivity;

C51H60O11P2; hydrogen; Rh nonanoate in toluene T=120°C; P=15001.5 Torr; 3 h; Inert atmosphere; Product distribution / selectivity;

[rhodium(I)(carbonyl)2(acetylacetonate)]; C72H46F24P4; hydrogen in toluene T=125°C; P=3800.26 Torr; 2 h; Autoclave; regioselective reaction;

in hexane; benzene a mixt. of Cp2ZrHCl and 3-octene in benzene was stirred for ca. 2 h at room temp. under N2, a soln. of anhyd. SnCl4 in n-hexane was added dropwise (Cp2ZrHCl/SnCl4 ratio 2:1), stirred for a further 1 h 30 min; hexane was added, ppt. of Cp2ZrCl2 was filtered off, filtrate was concd., residue extd. with hexane, exts. were combined, concd., dild. with methanol; (octyl)SnCl3 content was detd. by titrn. with 0.02 M EDTA;

bis(1,5-cyclooctadiene)nickel (0); tris(n-hexyl)aluminium in n-heptane T=80°C; 2 h; Product distribution / selectivity;

C51H60O11P2; hydrogen; Rh nonanoate in toluene T=120°C; P=15001.5 Torr; 3 h; Inert atmosphere; Product distribution / selectivity;

[rhodium(I)(carbonyl)2(acetylacetonate)]; C72H46F24P4; hydrogen in toluene T=125°C; P=3800.26 Torr; 2 h; Autoclave; regioselective reaction;