1: 28 percent / iodine / CHCl3 / 24 h / Ambient temperature
2: 15 percent / Adogen 464, sodium sulphide nonahydrate / CHCl3; H2O / 1 h / Ambient temperature
View Scheme
参考文献
Cambie, Richard C.; Mayer, Gregory D.; Rutledge, Peter S.; Woodgate, Paul D.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 52 - 57
[Rh(C8H12)((C6H5)2P(CH2)4P(C6H5)2)]BF4*C4H8O; B(C6F5)3 in further solvent(s)
(N2); treatment of octene with pinacol borane in dichloroethane at -20°C in presence of rhodium compd. and boron compd. for 24 h; GC anal.;
参考文献
Lata, Christopher J.; Crudden, Cathleen M.
Journal of the American Chemical Society, 2010 , vol. 132, # 1 p. 131 - 137