1: With Rhodium trichloride; boron trifluoride-tetrahydrofuran complex in tetrahydrofuran T=24°C; 2 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran; water T=24°C; Further stages.;
参考文献
Morrill, Terence C.; D'Souza, Christopher A.; Yang, Lu; Sampognaro, Anthony J.
Journal of Organic Chemistry, 2002 , vol. 67, # 8 p. 2481 - 2484
1: With diMe-Imd-BH3; bis-(trifluoromethylsulphonyl)amine in dichloromethane T=50°C; 2 h; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in methanol; dichloromethane; water T=25°C; 16 h;
参考文献
Prokofjevs, Aleksandrs; Boussonniere, Anne; Li, Linfeng; Bonin, Helene; Lacote, Emmanuel; Curran, Dennis P.; Vedejs, Edwin
Journal of the American Chemical Society, 2012 , vol. 134, # 29 p. 12281 - 12288
1: With diMe-Imd-BH3; bis-(trifluoromethylsulphonyl)amine in dichloromethane T=25°C; 1.5 h; Inert atmosphere; 2: With dihydrogen peroxide; sodium hydroxide in methanol; dichloromethane; water T=25°C; 16 h;
参考文献
Prokofjevs, Aleksandrs; Boussonniere, Anne; Li, Linfeng; Bonin, Helene; Lacote, Emmanuel; Curran, Dennis P.; Vedejs, Edwin
Journal of the American Chemical Society, 2012 , vol. 134, # 29 p. 12281 - 12288
1: trans-4-octene; 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane With triphenylphosphine; tetrakis-(ethylene)-μ,μ'-dichlorodirhodium(I) in dichloromethane 0.5 h; 2: dichloromethane With n-butyllithium in tetrahydrofuran T=-78 - 20°C; 3: With dihydrogen peroxide; sodium carbonate in tetrahydrofuran; water T=0 - 20°C;
参考文献
Edwards, David R.; Crudden, Cathleen M.; Yam, Katherine
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 1 p. 50 - 54
Marinescu, Smaranda C.; Levine, Daniel S.; Zhao, Yu; Schrock, Richard R.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 30 p. 11512 - 11514
