3-异丙基-alpha,alpha-二甲基苄醇合成路线 （共 7 条）
反应条件
sodium hydroxide in water; isobutyl methylketone T=90°C; Heating / reflux;
参考文献
Indspec Chemical Corporation
Patent: US6350921 B1, 2002 ;
Location in patent: Example 3 ;
反应条件
sodium hydroxide; 3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene in water T=90°C;
参考文献
Indspec Chemical Corporation
Patent: US6350921 B1, 2002 ;
Location in patent: Example 1 ;
反应条件
in various solvent(s) T=110°C; thermal decomposition, oth. temperature; Rate constant;
参考文献
Tovstokhat'ko, F. I.; Ovchinnikov, V. I.; Potekhin, V. M.
J. Appl. Chem. USSR (Engl. Transl.), 1980 , vol. 53, # 10 p. 2286 - 2290,1737 - 1741
反应条件
sodium sulfite in water; isobutyl methylketone Heating / reflux;
参考文献
Indspec Chemical Corporation
Patent: US6350921 B1, 2002 ;
Location in patent: Example 2 ;
反应条件
NADH-H+; cytochrome P450cam; putidaredoxin reductase; catalase; putidaredoxin T=25°C; 1.5 h; catalytic turnover of xenobiotics by cytochrome P450cam; substrate specificity; formation of metabolites; O2 and NADH consumption, production of H2O2; Product distribution;
参考文献
Zhang, Zhoupeng; Sibbesen, Ole; Johnson, Roy A.; Ortiz De Montellano, Paul R.
Bioorganic and Medicinal Chemistry, 1998 , vol. 6, # 9 p. 1501 - 1508
反应条件
magnesium naphthenate T=110°C; other temperature 120 deg C, with or without inhibitor and catalyst; Rate constant;
参考文献
Capp; Hawkins
Journal of the Chemical Society, 1953 , p. 4106
反应条件
oxygen; 1,10-phenanthroline; magnesium naphthenate T=80 - 120°C; E(act.) for various reaction products formation, other catalyst; Rate constantKineticsThermodynamic data;
参考文献
Tovstokhat'ko, F. I.; Moshchenko, V. S.; Potekhin, V. M.; Ovchinnikov, V. I.; Kozlov, S. K.; Mushenko, V. D.
J. Appl. Chem. USSR (Engl. Transl.), 1982 , vol. 55, # 3 p. 658 - 662,597 - 601
