三三(2,2,6,6-四甲基-3,5-庚二酮酸)钴(III)合成路线 （共 7 条）
反应条件
air in hexane reflux for 3 d; cooling to room temp., filtering, drying at 60 °C, re-crystn. from EtOH, elem. anal., an unidentified solid wss also formed;
参考文献
Ahmed; Fjellvag, Helmer; Kjekshus, Arne; Dietzel, Pascal D. C.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 2 p. 247 - 254
反应条件
air in further solvent(s) dione-compd. was used as solvent, reflux for 5 h; cooling to room temp., filtering, drying at 60 °C, re-crystn. from EtOH, elem. anal.;
参考文献
Ahmed; Fjellvag, Helmer; Kjekshus, Arne; Dietzel, Pascal D. C.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 2 p. 247 - 254
反应条件
O2 in ethanol reflux for 5 h; cooling to room temp., filtering and open to air evapn. to dryness followed re-dissoln. in EtOH (twice), filtering, vac. drying at 60 °C,recrystn. from EtOH, elem. anal.;
参考文献
Ahmed; Fjellvag, Helmer; Kjekshus, Arne; Dietzel, Pascal D. C.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 2 p. 247 - 254
反应条件
O2 in n-heptane reflux for 3 d; cooling to room temp., filtering, drying at 60 °C, re-crystn. from EtOH, elem. anal.; an amorphous product was also formed;
参考文献
Ahmed; Fjellvag, Helmer; Kjekshus, Arne; Dietzel, Pascal D. C.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 2 p. 247 - 254
反应条件
O2 in further solvent(s) dione-compd. was used as solvent, reflux for 5 h; cooling to room temp., filtering, drying at 60 °C, re-crystn. from EtOH, elem. anal.;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 634, # 2 p. 247 - 254
反应条件
in neat (no solvent) storage at room temp. for a long period of time;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 634, # 2 p. 247 - 254
反应条件
in neat (no solvent) storage at room temp. for a long period of time;
参考文献
Ahmed; Fjellvag, Helmer; Kjekshus, Arne; Dietzel, Pascal D. C.
Zeitschrift fur Anorganische und Allgemeine Chemie, 2008 , vol. 634, # 2 p. 247 - 254
